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- Manganese(III)_acetate abstract "Manganese(III) acetate is an inorganic compound that is used as an oxidizing agent in organic synthesis and materials science. Like the analogous acetates of iron and chromium, it is an oxygen-centered coordination complex containing three manganese atoms bridged by acetate units. The anhydrous form of this compound crystallizes as a linear coordination polymer, with an additional acetic acid molecule bridging between manganese atoms on consecutive three-manganese clusters. The chemical is therefore not a simple metal acetate ionic compound nor does the actual structure of it reflect the simple "Mn(OAc)3" chemical formula that is commonly given. It is usually used as the dihydrate, though the anhydrous form is also used in some situations. The dihydrate is prepared by reacting potassium permanganate and manganese(II) acetate in acetic acid; addition of acetic anhydride to the reaction produces the anhydrous form.Mangese triacetate has been used as a single electron oxidant. It can oxidize alkenes via addition of acetic acid to form lactones. This process is thought to proceed via the formation of a •CH2CO2H radical intermediate, which then reacts with the alkene, followed by additional oxidation steps and finally ring closure. When the alkene is not symmetric, the major product depends on the nature of the alkene, and is consistent with initial formation of the more stable radical (among the two carbons of the alkene) followed by ring closure onto the more stable conformation of the intermediate.When reacted with enones, the carbon on the other side of the carbonyl reacts rather than the alkene portion, leading to α'-acetoxy enones. In this process, the carbon next to the carbonyl is oxidized by the manganese, followed by transfer of acetate from the manganese to it.It can similarly oxidize β-ketoesters at the α carbon, and this intermediate can react with various other structures, including halides and alkenes (see: manganese-mediated coupling reactions). One extension of this idea is the cyclization of the ketoester portion of the molecule with an alkene elsewhere in the same structure.".
- Manganese(III)_acetate iupacName "Manganese triacetate".
- Manganese(III)_acetate thumbnail Mn3O(OAc)6.png?width=300.
- Manganese(III)_acetate wikiPageID "13491397".
- Manganese(III)_acetate wikiPageRevisionID "606762868".
- Manganese(III)_acetate hasPhotoCollection Manganese(III)_acetate.
- Manganese(III)_acetate imagefile "Mn3O6.png".
- Manganese(III)_acetate iupacname "Manganese triacetate".
- Manganese(III)_acetate name "Manganese Triacetate".
- Manganese(III)_acetate othernames "Manganese triacetate dihydrate; Manganese acetate dihydrate".
- Manganese(III)_acetate verifiedrevid "400295665".
- Manganese(III)_acetate watchedfields "changed".
- Manganese(III)_acetate subject Category:Acetates.
- Manganese(III)_acetate subject Category:Manganese_compounds.
- Manganese(III)_acetate subject Category:Oxidizing_agents.
- Manganese(III)_acetate type Abstraction100002137.
- Manganese(III)_acetate type Acetate114599806.
- Manganese(III)_acetate type Acetates.
- Manganese(III)_acetate type Chemical114806838.
- Manganese(III)_acetate type Cognition100023271.
- Manganese(III)_acetate type Compound105870180.
- Manganese(III)_acetate type Compound114818238.
- Manganese(III)_acetate type Concept105835747.
- Manganese(III)_acetate type Content105809192.
- Manganese(III)_acetate type Idea105833840.
- Manganese(III)_acetate type ManganeseCompounds.
- Manganese(III)_acetate type Material114580897.
- Manganese(III)_acetate type Matter100020827.
- Manganese(III)_acetate type Part113809207.
- Manganese(III)_acetate type PhysicalEntity100001930.
- Manganese(III)_acetate type PsychologicalFeature100023100.
- Manganese(III)_acetate type Relation100031921.
- Manganese(III)_acetate type Salt115010703.
- Manganese(III)_acetate type Substance100019613.
- Manganese(III)_acetate type Whole105869584.
- Manganese(III)_acetate type ChemicalCompound.
- Manganese(III)_acetate type ChemicalSubstance.
- Manganese(III)_acetate type ChemicalSubstanceType.
- Manganese(III)_acetate type ChemicalObject.
- Manganese(III)_acetate type Thing.
- Manganese(III)_acetate comment "Manganese(III) acetate is an inorganic compound that is used as an oxidizing agent in organic synthesis and materials science. Like the analogous acetates of iron and chromium, it is an oxygen-centered coordination complex containing three manganese atoms bridged by acetate units. The anhydrous form of this compound crystallizes as a linear coordination polymer, with an additional acetic acid molecule bridging between manganese atoms on consecutive three-manganese clusters.".
- Manganese(III)_acetate label "Mangan(III)-acetat".
- Manganese(III)_acetate label "Manganese(III) acetate".
- Manganese(III)_acetate label "乙酸锰(III)".
- Manganese(III)_acetate sameAs Mangan(III)-acetat.
- Manganese(III)_acetate sameAs m.03c729m.
- Manganese(III)_acetate sameAs Q906315.
- Manganese(III)_acetate sameAs Q906315.
- Manganese(III)_acetate sameAs Manganese(III)_acetate.
- Manganese(III)_acetate wasDerivedFrom Manganese(III)_acetate?oldid=606762868.
- Manganese(III)_acetate depiction Mn3O(OAc)6.png.
- Manganese(III)_acetate isPrimaryTopicOf Manganese(III)_acetate.
- Manganese(III)_acetate name "Manganese Triacetate".