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- Metal_bis(trimethylsilyl)amides abstract "Metal bis(trimethylsilyl)amides (often abbreviated as metal silylamides) are coordination complexes composed of a cationic metal with anionic bis(trimethylsilyl)amide ligands and are part of a broader category of metal amides.Metal bis(trimethylsilyl)amide complexes are lipophilic due to the ligand and hence are soluble in a range of nonpolar organic solvents, this often makes them more reactive than the corresponding metal halides, which can difficult to solubilise. The steric bulk of the ligands causes their complexes to be discrete and monomeric (with the exception of group 1 complexes). Having a built-in base, these compounds conveniently react with protic ligand precursors to give other metal complexes. The class of ligands and pioneering studies on their coordination compounds were described by Bürger and Wannagat.The ligands are often denoted hmds (e.g. M(N(SiMe3)2)3 = M(hmds)3) in reference to the hexamethyldisilazide from which they are prepared.".
- Metal_bis(trimethylsilyl)amides thumbnail Hmds_ligand.png?width=300.
- Metal_bis(trimethylsilyl)amides wikiPageID "32471219".
- Metal_bis(trimethylsilyl)amides wikiPageRevisionID "586213128".
- Metal_bis(trimethylsilyl)amides hasPhotoCollection Metal_bis(trimethylsilyl)amides.
- Metal_bis(trimethylsilyl)amides subject Category:Bis(trimethylsilyl)amides.
- Metal_bis(trimethylsilyl)amides subject Category:Coordination_compounds.
- Metal_bis(trimethylsilyl)amides comment "Metal bis(trimethylsilyl)amides (often abbreviated as metal silylamides) are coordination complexes composed of a cationic metal with anionic bis(trimethylsilyl)amide ligands and are part of a broader category of metal amides.Metal bis(trimethylsilyl)amide complexes are lipophilic due to the ligand and hence are soluble in a range of nonpolar organic solvents, this often makes them more reactive than the corresponding metal halides, which can difficult to solubilise.".
- Metal_bis(trimethylsilyl)amides label "Metal bis(trimethylsilyl)amides".
- Metal_bis(trimethylsilyl)amides sameAs m.0h1hw27.
- Metal_bis(trimethylsilyl)amides sameAs Q6822720.
- Metal_bis(trimethylsilyl)amides sameAs Q6822720.
- Metal_bis(trimethylsilyl)amides wasDerivedFrom Metal_bis(trimethylsilyl)amides?oldid=586213128.
- Metal_bis(trimethylsilyl)amides depiction Hmds_ligand.png.
- Metal_bis(trimethylsilyl)amides isPrimaryTopicOf Metal_bis(trimethylsilyl)amides.
