Matches in DBpedia 2014 for { <http://dbpedia.org/resource/Boord_olefin_synthesis> ?p ?o. }
Showing items 1 to 28 of
28
with 100 items per page.
- Boord_olefin_synthesis abstract "The Boord olefin synthesis is an organic reaction forming alkenes from ethers carrying a halogen atom 2 carbons removed from the oxygen atom (β-halo-ethers) catalyzed by a metal such as magnesium or zinc. The reaction, discovered by Cecil E. Boord in 1930 is a classic named reaction with high yields and broad scope.The Boord olefin synthesisThe reaction type is an elimination reaction with magnesium forming an intermediate Grignard reagent. The alkoxy group is a poor leaving group and therefore an E1cB elimination reaction mechanism is proposed. The original publication describes the organic synthesis of the compound isoheptene in several steps.Boord synthesis of isoheptene 1930In a 1931 publication the scope is extended to 1,4-dienes with magnesium replaced by zinc (see also: Barbier reaction). In the first part of the reaction the allyl Grignard acts as a nucleophile in nucleophilic aliphatic substitution. Boord diene synthesis 1931↑ ↑ 2.0 2.1 ↑".
- Boord_olefin_synthesis thumbnail BoordReactionOverview.png?width=300.
- Boord_olefin_synthesis wikiPageID "11839239".
- Boord_olefin_synthesis wikiPageRevisionID "549829031".
- Boord_olefin_synthesis hasPhotoCollection Boord_olefin_synthesis.
- Boord_olefin_synthesis subject Category:Name_reactions.
- Boord_olefin_synthesis subject Category:Organic_reactions.
- Boord_olefin_synthesis type ChemicalProcess113446390.
- Boord_olefin_synthesis type ChemicalReaction113447361.
- Boord_olefin_synthesis type NameReactions.
- Boord_olefin_synthesis type NaturalProcess113518963.
- Boord_olefin_synthesis type OrganicReactions.
- Boord_olefin_synthesis type PhysicalEntity100001930.
- Boord_olefin_synthesis type Process100029677.
- Boord_olefin_synthesis comment "The Boord olefin synthesis is an organic reaction forming alkenes from ethers carrying a halogen atom 2 carbons removed from the oxygen atom (β-halo-ethers) catalyzed by a metal such as magnesium or zinc. The reaction, discovered by Cecil E. Boord in 1930 is a classic named reaction with high yields and broad scope.The Boord olefin synthesisThe reaction type is an elimination reaction with magnesium forming an intermediate Grignard reagent.".
- Boord_olefin_synthesis label "Boord olefin synthesis".
- Boord_olefin_synthesis label "Boord-Olefin-Synthese".
- Boord_olefin_synthesis label "Boord烯烃合成".
- Boord_olefin_synthesis label "Síntesis de olefinas de Boord".
- Boord_olefin_synthesis sameAs Boord-Olefin-Synthese.
- Boord_olefin_synthesis sameAs Síntesis_de_olefinas_de_Boord.
- Boord_olefin_synthesis sameAs m.02rv56z.
- Boord_olefin_synthesis sameAs Q4943770.
- Boord_olefin_synthesis sameAs Q4943770.
- Boord_olefin_synthesis sameAs Boord_olefin_synthesis.
- Boord_olefin_synthesis wasDerivedFrom Boord_olefin_synthesis?oldid=549829031.
- Boord_olefin_synthesis depiction BoordReactionOverview.png.
- Boord_olefin_synthesis isPrimaryTopicOf Boord_olefin_synthesis.