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Macrophomic_acid abstract "Macrophomic acid is a fungal metabolite isolated from the fungus Macrophoma commelinae. The enzyme macrophomate synthase converts 5-acetyl-4-methoxy-6-methyl-2-pyrone to 4-acetyl-3-methoxy-5-methyl-benzoic acid (macrophomic acid) through an unusual intermolecular Diels-Alder reaction (Scheme 1). The pathway to formation of macrophomic acid suggests that the enzyme is a natural Diels-Alderase. Formation of this type of aromatic ring compound normally proceeds via the shikimate and polyketide pathways; however, the production of macrophomic acid by macrophomate synthase proceeds totally differently. Learning about the production of macrophomic acid by a possible natural Diels-Alderase enzyme is important in understanding enzyme catalytic mechanisms. This knowledge can then be applied to organic synthesis.File:Scheme 1 macrophomic acid.gif".
Macrophomic_acid iupacName "4-acetyl-3-methoxy-5-methylbenzoic acid".
Macrophomic_acid thumbnail Macrophomic_acid.svg?width=300.
Macrophomic_acid wikiPageID "23184842".
Macrophomic_acid wikiPageRevisionID "575373865".
Macrophomic_acid hasPhotoCollection Macrophomic_acid.
Macrophomic_acid imagefile "macrophomic acid.svg".
Macrophomic_acid imagesize "200".
Macrophomic_acid iupacname "4".
Macrophomic_acid verifiedrevid "422660555".
Macrophomic_acid subject Category:Aromatic_ketones.
Macrophomic_acid subject Category:Benzoic_acids.
Macrophomic_acid subject Category:Dicarboxylic_acids.
Macrophomic_acid subject Category:Phenol_ethers.
Macrophomic_acid type Abstraction100002137.
Macrophomic_acid type Acid114607521.
Macrophomic_acid type AromaticKetones.
Macrophomic_acid type BenzoicAcid114775321.
Macrophomic_acid type BenzoicAcids.
Macrophomic_acid type CarboxylicAcid114739360.
Macrophomic_acid type Chemical114806838.
Macrophomic_acid type Compound114818238.
Macrophomic_acid type Element114840755.
Macrophomic_acid type Ketone114926294.
Macrophomic_acid type Material114580897.
Macrophomic_acid type Matter100020827.
Macrophomic_acid type OrganicCompound114727670.
Macrophomic_acid type Part113809207.
Macrophomic_acid type PhenolEthers.
Macrophomic_acid type PhysicalEntity100001930.
Macrophomic_acid type Quintessence114847103.
Macrophomic_acid type Relation100031921.
Macrophomic_acid type Substance100019613.
Macrophomic_acid type ChemicalCompound.
Macrophomic_acid type ChemicalSubstance.
Macrophomic_acid type ChemicalSubstanceType.
Macrophomic_acid type ChemicalObject.
Macrophomic_acid type Thing.
Macrophomic_acid comment "Macrophomic acid is a fungal metabolite isolated from the fungus Macrophoma commelinae. The enzyme macrophomate synthase converts 5-acetyl-4-methoxy-6-methyl-2-pyrone to 4-acetyl-3-methoxy-5-methyl-benzoic acid (macrophomic acid) through an unusual intermolecular Diels-Alder reaction (Scheme 1). The pathway to formation of macrophomic acid suggests that the enzyme is a natural Diels-Alderase.".
Macrophomic_acid label "Macrophomic acid".
Macrophomic_acid sameAs m.064kx_3.
Macrophomic_acid sameAs Q6725521.
Macrophomic_acid sameAs Q6725521.
Macrophomic_acid sameAs Macrophomic_acid.
Macrophomic_acid wasDerivedFrom Macrophomic_acid?oldid=575373865.
Macrophomic_acid depiction Macrophomic_acid.svg.
Macrophomic_acid isPrimaryTopicOf Macrophomic_acid.