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- Methyl_bisulfate abstract "Methyl bisulfate is a chemical compound with the molecular formula CH3OSO3H. This compound is the mono-methyl ester of sulfuric acid. The significance of methyl bisulfate is that it is an intermediate in the hydrolysis of the important reagent dimethyl sulfate, (CH3)2SO4:(CH3)2SO4 + H2O → (CH3)HSO4 + CH3OHMethyl bisulfate is an acid:(CH3)HSO4 → (CH3)SO4- + H+Methyl bisulfate came into the public view in 1993 with the discovery that certain mercury compounds catalyze the conversion of methane to methylbisulfate in good yields with excellent selectivity in concentrated sulfuric acid. However, because of the toxicity and concerns with the use of mercury it wasn't until 1998 when platinum complexes were found that catalyze the reaction of CH4 by SO3 and O2 that it came into the limelight:CH4 + SO3 + 1/2 O2 → (CH3)HSO4This discovery pointed to a possible method for upgrading inexpensive and abundantly available methane (natural gas) into methanol, which is both a more useful chemical and more easily shipped than methane. The process is proposed to proceed via an intermediate containing the Pt-CH3 group.Salts of (CH3)SO4- are commercially available, e.g. tris(2-hydroxyethyl)methylammonium methylsulfate (CAS #29463-06-7).".
- Methyl_bisulfate thumbnail Methyl_hydrogen_sulfate.png?width=300.
- Methyl_bisulfate wikiPageID "4963691".
- Methyl_bisulfate wikiPageRevisionID "598538638".
- Methyl_bisulfate hasPhotoCollection Methyl_bisulfate.
- Methyl_bisulfate imagealt "Ball-and-stick model".
- Methyl_bisulfate imagealt "Skeletal formula".
- Methyl_bisulfate imagefile "Methyl bisulfate-Molecule-3D-balls-by-AHRLS 2011.png".
- Methyl_bisulfate imagefile "Methyl hydrogen sulfate.png".
- Methyl_bisulfate imagesize "150".
- Methyl_bisulfate imagesize "160".
- Methyl_bisulfate othernames "Methyl sulfate; Methylsulfuric acid; Methyl hydrogen sulfate; Monomethyl sulfate".
- Methyl_bisulfate verifiedfields "changed".
- Methyl_bisulfate verifiedrevid "443004403".
- Methyl_bisulfate subject Category:Methyl_esters.
- Methyl_bisulfate subject Category:Organosulfates.
- Methyl_bisulfate type Abstraction100002137.
- Methyl_bisulfate type Chemical114806838.
- Methyl_bisulfate type Compound114818238.
- Methyl_bisulfate type Ester114850483.
- Methyl_bisulfate type Material114580897.
- Methyl_bisulfate type Matter100020827.
- Methyl_bisulfate type MethylEsters.
- Methyl_bisulfate type OrganicCompound114727670.
- Methyl_bisulfate type Part113809207.
- Methyl_bisulfate type PhysicalEntity100001930.
- Methyl_bisulfate type Relation100031921.
- Methyl_bisulfate type Substance100019613.
- Methyl_bisulfate type ChemicalCompound.
- Methyl_bisulfate type ChemicalSubstance.
- Methyl_bisulfate type ChemicalSubstanceType.
- Methyl_bisulfate type ChemicalObject.
- Methyl_bisulfate type Thing.
- Methyl_bisulfate comment "Methyl bisulfate is a chemical compound with the molecular formula CH3OSO3H. This compound is the mono-methyl ester of sulfuric acid.".
- Methyl_bisulfate label "Acide méthylsulfurique".
- Methyl_bisulfate label "Methyl bisulfate".
- Methyl_bisulfate label "Wodorosiarczan metylu".
- Methyl_bisulfate sameAs Acide_méthylsulfurique.
- Methyl_bisulfate sameAs Wodorosiarczan_metylu.
- Methyl_bisulfate sameAs m.0cxc_3.
- Methyl_bisulfate sameAs Q2823290.
- Methyl_bisulfate sameAs Q2823290.
- Methyl_bisulfate sameAs Methyl_bisulfate.
- Methyl_bisulfate wasDerivedFrom Methyl_bisulfate?oldid=598538638.
- Methyl_bisulfate depiction Methyl_hydrogen_sulfate.png.
- Methyl_bisulfate isPrimaryTopicOf Methyl_bisulfate.