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- Midland_Alpine_borane_reduction abstract "The Midland Alpine borane reduction, or simply the Midland Reduction, allows for the asymmetric reduction of carbonyls (primarily ketones) to alcohols. It was developed in the late 1970s by Professor M. Mark Midland at the University of California, Riverside. The Midland Reduction is particularly useful because alpha-pinene is regenerated (although it is fairly cheap, so this matters less than with other chiral molecules), and because both enantiomers are commercially available. The Alpine borane can be synthesized by refluxing alpha-pinene and 9-BBN in THF. While both enantiomers of alpine borane are commercially available, it is far cheaper to make than buy.File:Alpineboranesynthesis.pngMany examples of the Midland reduction require a low steric group such as an alkyne or a nitrile so as to increase selectivity.The stereochemical control comes from coordination of the bulky borane to the carbonyl, followed by hydride transfer opposite the largest group.File:Alpineboranereductiontransitionstate.png".
- Midland_Alpine_borane_reduction thumbnail Alpineboranesynthesis.png?width=300.
- Midland_Alpine_borane_reduction wikiPageID "31128993".
- Midland_Alpine_borane_reduction wikiPageRevisionID "604811436".
- Midland_Alpine_borane_reduction hasPhotoCollection Midland_Alpine_borane_reduction.
- Midland_Alpine_borane_reduction subject Category:Name_reactions.
- Midland_Alpine_borane_reduction subject Category:Organic_redox_reactions.
- Midland_Alpine_borane_reduction type ChemicalProcess113446390.
- Midland_Alpine_borane_reduction type ChemicalReaction113447361.
- Midland_Alpine_borane_reduction type NameReactions.
- Midland_Alpine_borane_reduction type NaturalProcess113518963.
- Midland_Alpine_borane_reduction type OrganicRedoxReactions.
- Midland_Alpine_borane_reduction type PhysicalEntity100001930.
- Midland_Alpine_borane_reduction type Process100029677.
- Midland_Alpine_borane_reduction comment "The Midland Alpine borane reduction, or simply the Midland Reduction, allows for the asymmetric reduction of carbonyls (primarily ketones) to alcohols. It was developed in the late 1970s by Professor M. Mark Midland at the University of California, Riverside. The Midland Reduction is particularly useful because alpha-pinene is regenerated (although it is fairly cheap, so this matters less than with other chiral molecules), and because both enantiomers are commercially available.".
- Midland_Alpine_borane_reduction label "Midland Alpine borane reduction".
- Midland_Alpine_borane_reduction sameAs m.0gh8fcz.
- Midland_Alpine_borane_reduction sameAs Q6842304.
- Midland_Alpine_borane_reduction sameAs Q6842304.
- Midland_Alpine_borane_reduction sameAs Midland_Alpine_borane_reduction.
- Midland_Alpine_borane_reduction wasDerivedFrom Midland_Alpine_borane_reduction?oldid=604811436.
- Midland_Alpine_borane_reduction depiction Alpineboranesynthesis.png.
- Midland_Alpine_borane_reduction isPrimaryTopicOf Midland_Alpine_borane_reduction.