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- Rubottom_oxidation abstract "The Rubottom oxidation is a useful, high-yielding chemical reaction between silyl enol ethers and peroxyacids to give the corresponding α-hydroxy carbonyl product. The mechanism of the reaction was proposed in its original disclosure by A.G. Brook with further evidence later supplied by G.M. Rubottom. After a Prilezhaev-type oxidation of the silyl enol ether with the peroxyacid to form the siloxy oxirane intermediate, acid-catalyzed ring-opening yields an oxocarbenium ion. This intermediate then participates in a 1,4-silyl migration (Brook rearrangement) to give an α-siloxy carbonyl derivative that can be readily converted to the α-hydroxy carbonyl compound in the presence of acid, base, or a fluoride source.".
- Rubottom_oxidation thumbnail Rubottom_Mechanism4.png?width=300.
- Rubottom_oxidation wikiPageExternalLink Kurti%20L.,%20Czako%20B.%20Strategic%20Applications%20of%20Named%20Reactions%20in%20Organic%20Synthesis%20%28AP,%202005%29%28ISBN%200124297854%29%28810s%29.pdf.
- Rubottom_oxidation wikiPageExternalLink page8.html.
- Rubottom_oxidation wikiPageExternalLink HName%20Reactions%5B%E8%8B%B1%5DJie%20Jack%20Li.pdf.
- Rubottom_oxidation wikiPageExternalLink rubottom-oxidation.shtm.
- Rubottom_oxidation wikiPageID "7344825".
- Rubottom_oxidation wikiPageRevisionID "593385543".
- Rubottom_oxidation hasPhotoCollection Rubottom_oxidation.
- Rubottom_oxidation subject Category:Name_reactions.
- Rubottom_oxidation subject Category:Organic_redox_reactions.
- Rubottom_oxidation type ChemicalProcess113446390.
- Rubottom_oxidation type ChemicalReaction113447361.
- Rubottom_oxidation type NameReactions.
- Rubottom_oxidation type NaturalProcess113518963.
- Rubottom_oxidation type OrganicRedoxReactions.
- Rubottom_oxidation type PhysicalEntity100001930.
- Rubottom_oxidation type Process100029677.
- Rubottom_oxidation comment "The Rubottom oxidation is a useful, high-yielding chemical reaction between silyl enol ethers and peroxyacids to give the corresponding α-hydroxy carbonyl product. The mechanism of the reaction was proposed in its original disclosure by A.G. Brook with further evidence later supplied by G.M. Rubottom. After a Prilezhaev-type oxidation of the silyl enol ether with the peroxyacid to form the siloxy oxirane intermediate, acid-catalyzed ring-opening yields an oxocarbenium ion.".
- Rubottom_oxidation label "Rubottom oxidation".
- Rubottom_oxidation label "ルボトム酸化".
- Rubottom_oxidation label "鲁伯特姆氧化反应".
- Rubottom_oxidation sameAs ルボトム酸化.
- Rubottom_oxidation sameAs m.025zrxj.
- Rubottom_oxidation sameAs Q6133324.
- Rubottom_oxidation sameAs Q6133324.
- Rubottom_oxidation sameAs Rubottom_oxidation.
- Rubottom_oxidation wasDerivedFrom Rubottom_oxidation?oldid=593385543.
- Rubottom_oxidation depiction Rubottom_Mechanism4.png.
- Rubottom_oxidation isPrimaryTopicOf Rubottom_oxidation.