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- Schmidt_reaction abstract "The Schmidt reaction is an organic reaction involving alkyl migration over the carbon–nitrogen chemical bond in an azide with expulsion of nitrogen. A key reagent introducing this azide group is hydrazoic acid and the reaction product depends on the type of reactant: Carboxylic acids form amines through an isocyanate intermediate (1) and ketones form amides (2): A catalyst that can be a protic acid – usually sulfuric acid or a Lewis acid – is required. The reaction was discovered in 1924 by Karl Friedrich Schmidt (1887–1971), who successfully converted benzophenone and hydrazoic acid to benzanilide. It is a tool regularly used in organic chemistry for the synthesis of new organic compounds, for example, in that of the unusual 2-quinuclidone.".
- Schmidt_reaction thumbnail Schmidt_reaction.png?width=300.
- Schmidt_reaction wikiPageID "10221830".
- Schmidt_reaction wikiPageRevisionID "588467312".
- Schmidt_reaction author "Jade D. Nelson, Dilip P. Modi, and P. Andrew Evans".
- Schmidt_reaction author "Leo A. Paquette".
- Schmidt_reaction author "Scott Grecian and Jeff Aubé".
- Schmidt_reaction author "Stuart Lang and John Murphy".
- Schmidt_reaction collvol "10".
- Schmidt_reaction collvol "5".
- Schmidt_reaction collvolpages "207".
- Schmidt_reaction collvolpages "408".
- Schmidt_reaction hasPhotoCollection Schmidt_reaction.
- Schmidt_reaction pages "146".
- Schmidt_reaction pages "347".
- Schmidt_reaction prep "cv5p0408".
- Schmidt_reaction prep "v79p0165".
- Schmidt_reaction prep "v84p0347".
- Schmidt_reaction title "13".
- Schmidt_reaction title "Azide rearrangements in electron-deficient systems".
- Schmidt_reaction title "Photo-induced Ring Expansion of 1-Triisopropylsilyloxy-1-azidocyclohexane".
- Schmidt_reaction title "Synthesis of an N-Substituted Lactam using an Intramolecular Schmidt Reaction".
- Schmidt_reaction volume "55".
- Schmidt_reaction volume "84".
- Schmidt_reaction year "1973".
- Schmidt_reaction year "2004".
- Schmidt_reaction year "2006".
- Schmidt_reaction year "2007".
- Schmidt_reaction subject Category:Name_reactions.
- Schmidt_reaction subject Category:Rearrangement_reactions.
- Schmidt_reaction type ChemicalProcess113446390.
- Schmidt_reaction type ChemicalReaction113447361.
- Schmidt_reaction type NameReactions.
- Schmidt_reaction type NaturalProcess113518963.
- Schmidt_reaction type PhysicalEntity100001930.
- Schmidt_reaction type Process100029677.
- Schmidt_reaction type RearrangementReactions.
- Schmidt_reaction comment "The Schmidt reaction is an organic reaction involving alkyl migration over the carbon–nitrogen chemical bond in an azide with expulsion of nitrogen. A key reagent introducing this azide group is hydrazoic acid and the reaction product depends on the type of reactant: Carboxylic acids form amines through an isocyanate intermediate (1) and ketones form amides (2): A catalyst that can be a protic acid – usually sulfuric acid or a Lewis acid – is required.".
- Schmidt_reaction label "Reacción de Schmidt".
- Schmidt_reaction label "Reação de Schmidt".
- Schmidt_reaction label "Schmidt reaction".
- Schmidt_reaction label "Schmidt-Reaktion".
- Schmidt_reaction label "シュミット反応".
- Schmidt_reaction label "施密特反应".
- Schmidt_reaction sameAs Schmidt-Reaktion.
- Schmidt_reaction sameAs Reacción_de_Schmidt.
- Schmidt_reaction sameAs シュミット反応.
- Schmidt_reaction sameAs Reação_de_Schmidt.
- Schmidt_reaction sameAs m.02q5pm1.
- Schmidt_reaction sameAs Q903020.
- Schmidt_reaction sameAs Q903020.
- Schmidt_reaction sameAs Schmidt_reaction.
- Schmidt_reaction wasDerivedFrom Schmidt_reaction?oldid=588467312.
- Schmidt_reaction depiction Schmidt_reaction.png.
- Schmidt_reaction isPrimaryTopicOf Schmidt_reaction.