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- Sharpless_asymmetric_dihydroxylation abstract "Sharpless asymmetric dihydroxylation (also called the Sharpless bishydroxylation) is the chemical reaction of an alkene with osmium tetroxide in the presence of a chiral quinine ligand to form a vicinal diol.It is common practice to perform this reaction using a catalytic amount of osmium tetroxide, which after reaction is regenerated with either potassium ferricyanide or N-methylmorpholine N-oxide. This dramatically reduces the amount of the highly toxic and very expensive osmium tetroxide needed. These four reagents are commercially available premixed ("AD-mix"). The mixture containing (DHQ)2-PHAL is called AD-mix-α, and the mixture containing (DHQD)2-PHAL is called AD-mix-β.Such chiral diols are important in organic synthesis. The introduction of chirality into nonchiral reactants through usage of a chiral catalysts is an important concept in organic synthesis. This reaction was developed principally by K. Barry Sharpless building on the already known racemic Upjohn dihydroxylation, for which he was awarded a share of the 2001 Nobel Prize in Chemistry.".
- Sharpless_asymmetric_dihydroxylation thumbnail Sharpless_Dihydroxylation_Scheme.png?width=300.
- Sharpless_asymmetric_dihydroxylation wikiPageID "174773".
- Sharpless_asymmetric_dihydroxylation wikiPageRevisionID "602376037".
- Sharpless_asymmetric_dihydroxylation hasPhotoCollection Sharpless_asymmetric_dihydroxylation.
- Sharpless_asymmetric_dihydroxylation subject Category:Name_reactions.
- Sharpless_asymmetric_dihydroxylation subject Category:Organic_redox_reactions.
- Sharpless_asymmetric_dihydroxylation type ChemicalProcess113446390.
- Sharpless_asymmetric_dihydroxylation type ChemicalReaction113447361.
- Sharpless_asymmetric_dihydroxylation type NameReactions.
- Sharpless_asymmetric_dihydroxylation type NaturalProcess113518963.
- Sharpless_asymmetric_dihydroxylation type OrganicRedoxReactions.
- Sharpless_asymmetric_dihydroxylation type PhysicalEntity100001930.
- Sharpless_asymmetric_dihydroxylation type Process100029677.
- Sharpless_asymmetric_dihydroxylation comment "Sharpless asymmetric dihydroxylation (also called the Sharpless bishydroxylation) is the chemical reaction of an alkene with osmium tetroxide in the presence of a chiral quinine ligand to form a vicinal diol.It is common practice to perform this reaction using a catalytic amount of osmium tetroxide, which after reaction is regenerated with either potassium ferricyanide or N-methylmorpholine N-oxide.".
- Sharpless_asymmetric_dihydroxylation label "Asymetryczna dihydroksylacja Sharplessa".
- Sharpless_asymmetric_dihydroxylation label "Asymmetrische Dihydroxylierung".
- Sharpless_asymmetric_dihydroxylation label "Di-hidroxilação assimétrica de Sharpless".
- Sharpless_asymmetric_dihydroxylation label "Dihidroxilación asimétrica de Sharpless".
- Sharpless_asymmetric_dihydroxylation label "Diidrossilazione asimmetrica di Sharpless".
- Sharpless_asymmetric_dihydroxylation label "Sharpless asymmetric dihydroxylation".
- Sharpless_asymmetric_dihydroxylation label "Sharpless-bishydroxylering".
- Sharpless_asymmetric_dihydroxylation label "シャープレス不斉ジヒドロキシ化".
- Sharpless_asymmetric_dihydroxylation label "夏普莱斯不对称双羟基化反应".
- Sharpless_asymmetric_dihydroxylation sameAs Asymmetrische_Dihydroxylierung.
- Sharpless_asymmetric_dihydroxylation sameAs Dihidroxilación_asimétrica_de_Sharpless.
- Sharpless_asymmetric_dihydroxylation sameAs Diidrossilazione_asimmetrica_di_Sharpless.
- Sharpless_asymmetric_dihydroxylation sameAs シャープレス不斉ジヒドロキシ化.
- Sharpless_asymmetric_dihydroxylation sameAs Sharpless-bishydroxylering.
- Sharpless_asymmetric_dihydroxylation sameAs Asymetryczna_dihydroksylacja_Sharplessa.
- Sharpless_asymmetric_dihydroxylation sameAs Di-hidroxilação_assimétrica_de_Sharpless.
- Sharpless_asymmetric_dihydroxylation sameAs m.017lyy.
- Sharpless_asymmetric_dihydroxylation sameAs Q752651.
- Sharpless_asymmetric_dihydroxylation sameAs Q752651.
- Sharpless_asymmetric_dihydroxylation sameAs Sharpless_asymmetric_dihydroxylation.
- Sharpless_asymmetric_dihydroxylation wasDerivedFrom Sharpless_asymmetric_dihydroxylation?oldid=602376037.
- Sharpless_asymmetric_dihydroxylation depiction Sharpless_Dihydroxylation_Scheme.png.
- Sharpless_asymmetric_dihydroxylation isPrimaryTopicOf Sharpless_asymmetric_dihydroxylation.