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- Shvo_catalyst abstract "The Shvo catalyst, named after Youval Shvo, is an organoruthenium compound that is used for transfer hydrogenation. Related derivatives are known where p-tolyl replaces some of the phenyl groups. The compound is of academic interest as an early example of a catalyst for transfer hydrogenation that operates by an "outer sphere mechanism." Commonly, industrial hydrogenation processes involve heterogeneous catalysts containing one or more transition metals. While this approach facilitates efficient production on an industrial scale, heterogeneous catalysis is not always suitable for the asymmetric synthesis of more structurally complex molecules, which demands the increased versatility precluded by necessary interaction with a solid metal surface.One half of the 2001 Nobel Prize in Chemistry was awarded jointly to William S. Knowles and Ryoji Noyori "for their work on chirally catalysed hydrogenation reactions", and the other half was awarded to K. Barry Sharpless "for his work on chirally catalysed oxidation reactions", highlighting the growing importance of homogeneous catalysis as an industrially applicable redox technique for asymmetric synthesis. Shvo's catalyst represents a subset of homogeneous hydrogenation catalysts that involves both metal and ligand in its mechanism, and it therefore presents unique opportunities for customizing selectivity.".
- Shvo_catalyst iupacName "1-Hydroxytetraphenylcyclopentadienyl-(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)".
- Shvo_catalyst thumbnail ShvoCat.png?width=300.
- Shvo_catalyst wikiPageID "26660462".
- Shvo_catalyst wikiPageRevisionID "586835347".
- Shvo_catalyst hasPhotoCollection Shvo_catalyst.
- Shvo_catalyst imagefile "ShvoCat.png".
- Shvo_catalyst imagesize "200".
- Shvo_catalyst iupacname "1".
- Shvo_catalyst verifiedrevid "437050229".
- Shvo_catalyst subject Category:Carbonyl_complexes.
- Shvo_catalyst subject Category:Catalysts.
- Shvo_catalyst subject Category:Ruthenium_compounds.
- Shvo_catalyst type Abstraction100002137.
- Shvo_catalyst type Activator114723079.
- Shvo_catalyst type CarbonylComplexes.
- Shvo_catalyst type Catalyst114723628.
- Shvo_catalyst type Catalysts.
- Shvo_catalyst type Cognition100023271.
- Shvo_catalyst type Complex105870365.
- Shvo_catalyst type Compound105870180.
- Shvo_catalyst type Concept105835747.
- Shvo_catalyst type Content105809192.
- Shvo_catalyst type Idea105833840.
- Shvo_catalyst type Matter100020827.
- Shvo_catalyst type Part113809207.
- Shvo_catalyst type PhysicalEntity100001930.
- Shvo_catalyst type PsychologicalFeature100023100.
- Shvo_catalyst type Relation100031921.
- Shvo_catalyst type RutheniumCompounds.
- Shvo_catalyst type Substance100019613.
- Shvo_catalyst type Whole105869584.
- Shvo_catalyst type ChemicalCompound.
- Shvo_catalyst type ChemicalSubstance.
- Shvo_catalyst type ChemicalObject.
- Shvo_catalyst type Thing.
- Shvo_catalyst comment "The Shvo catalyst, named after Youval Shvo, is an organoruthenium compound that is used for transfer hydrogenation. Related derivatives are known where p-tolyl replaces some of the phenyl groups. The compound is of academic interest as an early example of a catalyst for transfer hydrogenation that operates by an "outer sphere mechanism." Commonly, industrial hydrogenation processes involve heterogeneous catalysts containing one or more transition metals.".
- Shvo_catalyst label "Catalyseur de Shvo".
- Shvo_catalyst label "Shvo catalyst".
- Shvo_catalyst sameAs Catalyseur_de_Shvo.
- Shvo_catalyst sameAs m.0b__t7l.
- Shvo_catalyst sameAs Q4788036.
- Shvo_catalyst sameAs Q4788036.
- Shvo_catalyst sameAs Shvo_catalyst.
- Shvo_catalyst wasDerivedFrom Shvo_catalyst?oldid=586835347.
- Shvo_catalyst depiction ShvoCat.png.
- Shvo_catalyst isPrimaryTopicOf Shvo_catalyst.