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- Swern_oxidation abstract "The Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol is oxidized to an aldehyde or ketone using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine. The reaction is known for its mild character and wide tolerance of functional groups.The by-products are dimethyl sulfide (Me2S), carbon monoxide (CO), carbon dioxide (CO2) and — when triethylamine is used as base — triethylammonium chloride (Et3NHCl). Two of the by-products, dimethyl sulfide and carbon monoxide, are very toxic volatile compounds, so the reaction and the work-up needs to be performed in a fume hood. Dimethyl sulfide is a volatile liquid (B.P. 37 °C) with an extremely unpleasant odour.Several reviews have been published.".
- Swern_oxidation thumbnail Swern_Oxidation_Scheme.png?width=300.
- Swern_oxidation wikiPageExternalLink swern-oxidation.shtm.
- Swern_oxidation wikiPageID "173870".
- Swern_oxidation wikiPageRevisionID "603032861".
- Swern_oxidation hasPhotoCollection Swern_oxidation.
- Swern_oxidation subject Category:Name_reactions.
- Swern_oxidation subject Category:Organic_redox_reactions.
- Swern_oxidation type ChemicalProcess113446390.
- Swern_oxidation type ChemicalReaction113447361.
- Swern_oxidation type NameReactions.
- Swern_oxidation type NaturalProcess113518963.
- Swern_oxidation type OrganicRedoxReactions.
- Swern_oxidation type PhysicalEntity100001930.
- Swern_oxidation type Process100029677.
- Swern_oxidation comment "The Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol is oxidized to an aldehyde or ketone using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine. The reaction is known for its mild character and wide tolerance of functional groups.The by-products are dimethyl sulfide (Me2S), carbon monoxide (CO), carbon dioxide (CO2) and — when triethylamine is used as base — triethylammonium chloride (Et3NHCl).".
- Swern_oxidation label "Ossidazione di Swern".
- Swern_oxidation label "Oxidación de Swern".
- Swern_oxidation label "Oxidação de Swern".
- Swern_oxidation label "Oxydation de Swern".
- Swern_oxidation label "Swern oxidation".
- Swern_oxidation label "Swern-Oxidation".
- Swern_oxidation label "Swern-oxidatie".
- Swern_oxidation label "スワーン酸化".
- Swern_oxidation label "斯文氧化反应".
- Swern_oxidation sameAs Swern-Oxidation.
- Swern_oxidation sameAs Oxidación_de_Swern.
- Swern_oxidation sameAs Oxydation_de_Swern.
- Swern_oxidation sameAs Ossidazione_di_Swern.
- Swern_oxidation sameAs スワーン酸化.
- Swern_oxidation sameAs Swern_산화반응.
- Swern_oxidation sameAs Swern-oxidatie.
- Swern_oxidation sameAs Oxidação_de_Swern.
- Swern_oxidation sameAs m.017g9s.
- Swern_oxidation sameAs Q899430.
- Swern_oxidation sameAs Q899430.
- Swern_oxidation sameAs Swern_oxidation.
- Swern_oxidation wasDerivedFrom Swern_oxidation?oldid=603032861.
- Swern_oxidation depiction Swern_Oxidation_Scheme.png.
- Swern_oxidation isPrimaryTopicOf Swern_oxidation.