Matches in DBpedia 2014 for { <http://dbpedia.org/resource/Wulff–Dötz_reaction> ?p ?o. }
Showing items 1 to 26 of
26
with 100 items per page.
- Wulff–Dötz_reaction abstract "The Wulff–Dötz reaction (also known as the Dötz reaction or the benzannulation reaction of the Fischer carbene complexes) is the chemical reaction of an aromatic or vinylic alkoxy pentacarbonyl chromium carbene complex with an alkyne and carbon monoxide to give a Cr(CO)3-coordinated substituted phenol. Several reviews have been published. It is named after the German chemist Karl Heinz Dötz (b. 1943) and the American chemist William D. Wulff (b. 1949) at Michigan State University. The reaction was first discovered by Karl Dötz and was extensively developed by his group and W. Wulff's group. They subsequently share the name of the reaction.The position of the substituents is highly predictable with the largest alkyne substituent (RL) neighboring the phenol and the smallest alkyne substituent (RS) neighboring the methoxy group . Hence, this reaction is more useful for terminal alkynes than internal alkynes.The phenol can be liberated from the chromium complex by a mild oxidation, such as ceric ammonium nitrate or air oxidation.Since this reaction can quickly generate complex phenolic compounds, the Wulff–Dötz reaction has been used most often in the synthesis of natural products, especially Vitamins E and K.".
- Wulff–Dötz_reaction thumbnail Wulffdotz3.png?width=300.
- Wulff–Dötz_reaction wikiPageID "6815145".
- Wulff–Dötz_reaction wikiPageRevisionID "564643968".
- Wulff–Dötz_reaction author "Timko, J. M.; Yamashita, A.".
- Wulff–Dötz_reaction collvol "9".
- Wulff–Dötz_reaction collvolpages "1".
- Wulff–Dötz_reaction journal Organic_Syntheses.
- Wulff–Dötz_reaction prep "cv9p0001".
- Wulff–Dötz_reaction title "Synthesis of 2-substituted naphthalenediol derivatives using chromium carbene complexes: 1-acetoxy-2-butyl-4-methoxynaphthalene".
- Wulff–Dötz_reaction year "1998".
- Wulff–Dötz_reaction subject Category:Addition_reactions.
- Wulff–Dötz_reaction subject Category:Carbon-carbon_bond_forming_reactions.
- Wulff–Dötz_reaction subject Category:Name_reactions.
- Wulff–Dötz_reaction comment "The Wulff–Dötz reaction (also known as the Dötz reaction or the benzannulation reaction of the Fischer carbene complexes) is the chemical reaction of an aromatic or vinylic alkoxy pentacarbonyl chromium carbene complex with an alkyne and carbon monoxide to give a Cr(CO)3-coordinated substituted phenol. Several reviews have been published. It is named after the German chemist Karl Heinz Dötz (b. 1943) and the American chemist William D. Wulff (b. 1949) at Michigan State University.".
- Wulff–Dötz_reaction label "Dötz-Reaktion".
- Wulff–Dötz_reaction label "Dötz反应".
- Wulff–Dötz_reaction label "Wulff–Dötz reaction".
- Wulff–Dötz_reaction label "デッツ反応".
- Wulff–Dötz_reaction sameAs Wulff%E2%80%93D%C3%B6tz_reaction.
- Wulff–Dötz_reaction sameAs Dötz-Reaktion.
- Wulff–Dötz_reaction sameAs デッツ反応.
- Wulff–Dötz_reaction sameAs Q689667.
- Wulff–Dötz_reaction sameAs Q689667.
- Wulff–Dötz_reaction wasDerivedFrom Wulff–Dötz_reaction?oldid=564643968.
- Wulff–Dötz_reaction depiction Wulffdotz3.png.