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- 1,3,5-Trithiane abstract "1,3,5-Trithiane is the chemical compound with the formula (CH2S)3. This heterocycle is the cyclic trimer of the otherwise unstable species thioformaldehyde. It consists of a six-membered ring with alternating methylene bridges and thioether groups. It is prepared by treatment of formaldehyde with hydrogen sulfide.Trithiane is a building block molecule in organic synthesis, being a masked source of formaldehyde. In one application, it is deprotonated with organolithium reagents to give the lithium derivative, which can be alkylated.(CH2S)3 + RLi → (CH2S)2(CHLiS) + RH(CH2S)2(CHLiS) + R’Br → (CH2S)2(CHR’S) + LiBr(CH2S)2(CHR’S) + H2O → R’CHO + ….Trithiane is the dithioacetal of formaldehyde. Other dithioacetals undergo similar reactions to the above.It is also a precursor to other organosulfur reagents. For example, chlorination in the presence of water affords the chloromethylsulfonyl chloride:(CH2S)3 + 9 Cl2 + 6 H2O → 3 ClCH2SO2Cl + 12 HCl↑ ↑ ↑ ↑".
- 1,3,5-Trithiane iupacName "1,3,5-Trithiane".
- 1,3,5-Trithiane thumbnail 1,3,5-Trithiane.png?width=300.
- 1,3,5-Trithiane wikiPageID "11740928".
- 1,3,5-Trithiane wikiPageRevisionID "602775770".
- 1,3,5-Trithiane hasPhotoCollection 1,3,5-Trithiane.
- 1,3,5-Trithiane imagefile "135".
- 1,3,5-Trithiane imagefilel "135".
- 1,3,5-Trithiane imagefiler "135".
- 1,3,5-Trithiane imagesize "100".
- 1,3,5-Trithiane iupacname "135".
- 1,3,5-Trithiane othernames "Thioformaldehyde trimer, Trimethylentrisulfide, Trimethylene trisulfide, Trithioformaldehyde, 1,3,5-Trithiacyclohexane, sym-Trithiane, Thioform, s-Trithiane".
- 1,3,5-Trithiane verifiedfields "changed".
- 1,3,5-Trithiane verifiedrevid "477204831".
- 1,3,5-Trithiane subject Category:Sulfur_heterocycles.
- 1,3,5-Trithiane type ChemicalCompound.
- 1,3,5-Trithiane type ChemicalSubstance.
- 1,3,5-Trithiane type ChemicalSubstanceType.
- 1,3,5-Trithiane type ChemicalObject.
- 1,3,5-Trithiane type Thing.
- 1,3,5-Trithiane comment "1,3,5-Trithiane is the chemical compound with the formula (CH2S)3. This heterocycle is the cyclic trimer of the otherwise unstable species thioformaldehyde. It consists of a six-membered ring with alternating methylene bridges and thioether groups. It is prepared by treatment of formaldehyde with hydrogen sulfide.Trithiane is a building block molecule in organic synthesis, being a masked source of formaldehyde.".
- 1,3,5-Trithiane label "1,3,5-Trithiane".
- 1,3,5-Trithiane label "1,3,5-trithiane".
- 1,3,5-Trithiane label "1,3,5-トリチアン".
- 1,3,5-Trithiane label "Тиоформальдегид".
- 1,3,5-Trithiane sameAs 1,3,5-trithiane.
- 1,3,5-Trithiane sameAs 1,3,5-トリチアン.
- 1,3,5-Trithiane sameAs m.02rqsnv.
- 1,3,5-Trithiane sameAs Q2356063.
- 1,3,5-Trithiane sameAs Q2356063.
- 1,3,5-Trithiane wasDerivedFrom 1,3,5-Trithiane?oldid=602775770.
- 1,3,5-Trithiane depiction 1,3,5-Trithiane.png.
- 1,3,5-Trithiane isPrimaryTopicOf 1,3,5-Trithiane.