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- 01GQZJRY3RJTZBFYHBF5MZ3NW0 classification A1.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 date "2023".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 language "eng".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 type journalArticle.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 hasPart 01GQZJXX871SVNFJZYJSWXV5C6.pdf.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 subject "Chemistry".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 doi "10.1038/s42004-022-00808-y".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 issn "2399-3669".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 issue "1".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 volume "6".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 abstract "Soft porous crystals, which are responsive to external stimuli such as temperature, pressure, or gas adsorption, are being extensively investigated for various technological applications. However, while substantial research has been devoted to stimuli-responsive metal-organic frameworks, structural flexibility in 3D covalent organic frameworks (COFs) remains ill understood, and is almost exclusively found in COFs exhibiting the diamondoid (dia) topology. Herein, we systemically investigate how the structural decoration of these 3D dia COFs & mdash;their specific building blocks and degree of interpenetration & mdash;as well as external triggers such as temperature and guest adsorption may promote or suppress their phase transformations, as captured by a collection of 2D free energy landscapes. Together, these provide a comprehensive understanding of the necessary conditions to design flexible diamondoid COFs. This study reveals how their flexibility originates from the balance between steric hindrance and dispersive interactions of the structural decoration, thereby providing insight into how new flexible 3D COFs can be designed.".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 author 1DA6787E-F0EE-11E1-A9DE-61C894A0A6B4.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 author 6C7C8F78-E4F5-11E2-B0A2-B95A10BDE39D.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 author F542886E-F0ED-11E1-A9DE-61C894A0A6B4.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 author F70EA0C8-F0EE-11E1-A197-91C894A0A6B4.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 author F80C8D06-F0ED-11E1-A9DE-61C894A0A6B4.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 dateCreated "2023-01-29T20:16:22Z".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 dateModified "2024-12-12T19:15:48Z".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 name "Exploring the phase stability in interpenetrated diamondoid covalent organic frameworks".
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 pagination urn:uuid:d2f422b7-98fa-4de1-9a5e-d304490327c7.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 publisher urn:uuid:7bf878ce-8b0a-431f-8090-f4b9b265148b.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 sameAs LU-01GQZJRY3RJTZBFYHBF5MZ3NW0.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 sourceOrganization urn:uuid:35f9725c-d7bc-4de6-9924-e2a55c893fc1.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 sourceOrganization urn:uuid:6b9a21ce-12f5-43a2-886c-e9f40891335a.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 sourceOrganization urn:uuid:a2e8555b-8f36-4b1a-8e30-2775053e8c4b.
- 01GQZJRY3RJTZBFYHBF5MZ3NW0 type A1.