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- 01J2HMKCXAEXY56T9VC7JE8H2D classification C3.
- 01J2HMKCXAEXY56T9VC7JE8H2D date "2024".
- 01J2HMKCXAEXY56T9VC7JE8H2D language "eng".
- 01J2HMKCXAEXY56T9VC7JE8H2D type conference.
- 01J2HMKCXAEXY56T9VC7JE8H2D hasPart 01J2HMSBHQ1BR8NVDQY1HE8K2N.pdf.
- 01J2HMKCXAEXY56T9VC7JE8H2D hasPart 01J2HMSMVPEF095BC5YTCEJB0J.pdf.
- 01J2HMKCXAEXY56T9VC7JE8H2D hasPart 01J7ZQ2TTERBWF2PDKM1YWSZPA.pdf.
- 01J2HMKCXAEXY56T9VC7JE8H2D subject "Earth and Environmental Sciences".
- 01J2HMKCXAEXY56T9VC7JE8H2D subject "Technology and Engineering".
- 01J2HMKCXAEXY56T9VC7JE8H2D presentedAt urn:uuid:145c5be9-1287-4b6d-9b80-4ea82a782696.
- 01J2HMKCXAEXY56T9VC7JE8H2D abstract "Visible light mediated heterogeneous photocatalysis of fungicide thiabendazole (model compound for pesticide), methlene blue (cationic dye), methy orange (anionic dye) and gas phase ethanol (indoor pollutant) was experimentally evaluated. Different photocatalytic active materials were used, e.g., porous organic polymers for comparison with (reduced) metal oxides, and both commercial and oxygen vacancy modified ZnO. Reversible adsorption in the dark and photocatalytic degradation under simulated light irradiation via different radical types were simultaneously modelled via coupled differential equations in both liquid phase and on the catalyst surface, taking into account the effect of light intensity and pH on the adsorption and degradation. The proposed kinetic models satisfactorily describe the various experimental data with deviations <5%. It was found that light intensity comes with a linear relation with both degradation rates in solution and on the catalyst surface, while it does not significantly affect the adsorption/desorption rates. Regarding the pH effect in relation to the speciation of the pollutants, it was found that different species have distinct adsorption and desorption coefficients. The models can be used to calculate the pKa values of model compounds in actual solution. Photocatalytic experiments under natural sunlight with variable light intensity (10 to 125 W/m²) were performed and the calculated responses correlate very well with the experimental data. Furthermore, the proposed models allow to correctly quantify the photocatalytic quantum yield, which is only based on the degradation of the actual pollutant without erroneously taking into account the additional removal by adsorption (Ranjbari et al., 2023).".
- 01J2HMKCXAEXY56T9VC7JE8H2D author A49F73A2-DBF2-11E9-B029-F6395707D3EF.
- 01J2HMKCXAEXY56T9VC7JE8H2D author F714BB94-F0ED-11E1-A9DE-61C894A0A6B4.
- 01J2HMKCXAEXY56T9VC7JE8H2D dateCreated "2024-07-11T19:33:54Z".
- 01J2HMKCXAEXY56T9VC7JE8H2D dateModified "2024-11-28T00:10:12Z".
- 01J2HMKCXAEXY56T9VC7JE8H2D name "Kinetic modeling for photocatalytic pollutant removal : effect of process variables, beyond the pseudo-first order approach".
- 01J2HMKCXAEXY56T9VC7JE8H2D pagination urn:uuid:effd9eaf-f45b-4206-af94-ef586230bb86.
- 01J2HMKCXAEXY56T9VC7JE8H2D sameAs LU-01J2HMKCXAEXY56T9VC7JE8H2D.
- 01J2HMKCXAEXY56T9VC7JE8H2D sourceOrganization urn:uuid:959310e6-b449-4b47-adc3-72fbd768c083.
- 01J2HMKCXAEXY56T9VC7JE8H2D sourceOrganization urn:uuid:f0a94022-479f-4b1f-a41e-0f0ea5eed23a.
- 01J2HMKCXAEXY56T9VC7JE8H2D type C3.