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- aggregation classification "A1".
- aggregation creator B412386.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2010".
- aggregation format "application/pdf".
- aggregation hasFormat 1004170.bibtex.
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- aggregation isPartOf urn:issn:1477-0520.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Asymmetric synthesis of new chiral N-sulfinyl 2,2-disubstituted aziridines by Grignard additions across alpha-chloro N-sulfinyl ketimines".
- aggregation abstract "Reaction of chiral alpha-chloro N-tert-butanesulfinyl ketimines with Grignard reagents afforded new chiral N-sulfinyl 2,2-disubstituted aziridines in good to excellent diastereomeric ratio (dr up to 98:2). The 1,2,2-trisubstituted aziridines were isolated in high overall yield (51-85%) and with excellent enantiomeric excess (> 98% ee). The stereoselectivity obtained in the Grignard addition is rationalized by the coordinating ability of the alpha-chloro atom resulting in the opposite stereochemical outcome as observed for nonfunctionalized N-sulfinyl ketimines".
- aggregation authorList BK730663.
- aggregation endPage "3258".
- aggregation issue "14".
- aggregation startPage "3251".
- aggregation volume "8".
- aggregation aggregates 1004216.
- aggregation isDescribedBy 1004170.
- aggregation similarTo c001471k.
- aggregation similarTo LU-1004170.