Matches in UGent Biblio for { <https://biblio.ugent.be/publication/1027212#aggregation> ?p ?o. }
Showing items 1 to 37 of
37
with 100 items per page.
- aggregation classification "A1".
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2010".
- aggregation format "application/pdf".
- aggregation hasFormat 1027212.bibtex.
- aggregation hasFormat 1027212.csv.
- aggregation hasFormat 1027212.dc.
- aggregation hasFormat 1027212.didl.
- aggregation hasFormat 1027212.doc.
- aggregation hasFormat 1027212.json.
- aggregation hasFormat 1027212.mets.
- aggregation hasFormat 1027212.mods.
- aggregation hasFormat 1027212.rdf.
- aggregation hasFormat 1027212.ris.
- aggregation hasFormat 1027212.txt.
- aggregation hasFormat 1027212.xls.
- aggregation hasFormat 1027212.yaml.
- aggregation isPartOf urn:issn:1477-0520.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Experimental and computational study of the ring opening of tricyclic oxanorbornenes to polyhydro isoindole phosphonates".
- aggregation abstract "Phosphonylated azaheterocycles are an important class of compounds with high biological potential as conformationally restricted bioisosteres of amino acids. Therefore, it is of interest to synthesize conformationally constrained amino phosphonates. We wanted to investigate possible routes via ring opening of alpha-amino phosphonates with an oxanorbornene skeleton, as these can be synthesized with high stereoselectivity. This was achieved using different Lewis acids, leading to a range of products. The reaction with TiCl4 and FeCl3 was modelled at a DFT level of theory to get insight in the pathways towards the corresponding products. To ease the work up, the Fe(III) catalyst was coated on montmorillonite clay, but this accelerated aromatization after ring opening. Quenching the FeCl3 catalyzed reaction mixture on celite caused complete aromatization.".
- aggregation authorList BK426765.
- aggregation endPage "3654".
- aggregation issue "16".
- aggregation startPage "3644".
- aggregation volume "8".
- aggregation aggregates 4133515.
- aggregation isDescribedBy 1027212.
- aggregation similarTo c002926b.
- aggregation similarTo LU-1027212.