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- aggregation classification "A1".
- aggregation creator B582496.
- aggregation creator B582497.
- aggregation creator B582498.
- aggregation creator person.
- aggregation date "2010".
- aggregation format "application/pdf".
- aggregation hasFormat 1072253.bibtex.
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- aggregation hasFormat 1072253.dc.
- aggregation hasFormat 1072253.didl.
- aggregation hasFormat 1072253.doc.
- aggregation hasFormat 1072253.json.
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- aggregation isPartOf urn:issn:0024-9297.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Copolymerization of 2-hydroxyethyl acrylate and 2-methoxyethyl acrylate via RAFT: kinetics and thermoresponsive properties".
- aggregation abstract "Kinetic studies of the (co)polymerization of 2-hydroxyethyl acrylate (H EA) and/or 2-methoxyethyl acrylate (M EA) via reversible addition fragmentation chain transfer polymerization (RAFT), using dibenzyltrithiocarbonate (DBTTC) as chain-transfer agent, resulting in well-defined copolymers, are presented. Both monomers were found to have equal reactivity revealing the formation of ideal random (azeotropic) copolymers. The thermoresponsive properties of aqueous solutions of the copolymers at 5 mg/ mL, depending on the polymer composition, the chain length, and the end-groups, were investigated. The cloud point (CP) of the synthesized copolymers increases with the content of HEA and decreases with the decreasing chain length. Exchanging one of the hydrophobic benzylic end-groups of the copolymers by isobutyronitrile resulted in more hydrophilic copolymers with significantly higher CP-temperatures. Thus, new potential biomaterials with an adjustable cloud point between 0 and 60 degrees C, showing a small hysteresis between heating and cooling, were successfully prepared.".
- aggregation authorList BK934364.
- aggregation endPage "7047".
- aggregation issue "17".
- aggregation startPage "7041".
- aggregation volume "43".
- aggregation aggregates 1072257.
- aggregation isDescribedBy 1072253.
- aggregation similarTo ma101122b.
- aggregation similarTo LU-1072253.