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- aggregation classification "A1".
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2010".
- aggregation format "application/pdf".
- aggregation hasFormat 1091561.bibtex.
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- aggregation isPartOf urn:issn:1477-0520.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Microwave-assisted regioselective ring opening of non-activated aziridines by lithium aluminium hydride".
- aggregation abstract "A new synthetic protocol for the LiAlH4-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corresponding beta-amino alcohols, which were then used as eligible substrates in the synthesis of 5-methylmorpholin-2-ones via condensation with glyoxal in THF. The same procedure was applied for the preparation of novel 5(R)- and 5(S)-methylmorpholin-2-ones starting from the corresponding enantiopure 2-(hydroxymethyl)aziridines. Additionally, 2-(methoxymethyl)- and 2-(phenoxymethyl)aziridines were treated with LiAlH4 under microwave irradiation, giving rise to either isopropylamines or 1-methoxypropan-2-amines depending on the reaction conditions.".
- aggregation authorList BK495291.
- aggregation endPage "4273".
- aggregation issue "19".
- aggregation startPage "4266".
- aggregation volume "8".
- aggregation aggregates 1091562.
- aggregation isDescribedBy 1091561.
- aggregation similarTo c004960c.
- aggregation similarTo LU-1091561.