Matches in UGent Biblio for { <https://biblio.ugent.be/publication/1167851#aggregation> ?p ?o. }
Showing items 1 to 34 of
34
with 100 items per page.
- aggregation classification "A1".
- aggregation creator B608409.
- aggregation creator B608410.
- aggregation creator person.
- aggregation date "2011".
- aggregation format "application/pdf".
- aggregation hasFormat 1167851.bibtex.
- aggregation hasFormat 1167851.csv.
- aggregation hasFormat 1167851.dc.
- aggregation hasFormat 1167851.didl.
- aggregation hasFormat 1167851.doc.
- aggregation hasFormat 1167851.json.
- aggregation hasFormat 1167851.mets.
- aggregation hasFormat 1167851.mods.
- aggregation hasFormat 1167851.rdf.
- aggregation hasFormat 1167851.ris.
- aggregation hasFormat 1167851.txt.
- aggregation hasFormat 1167851.xls.
- aggregation hasFormat 1167851.yaml.
- aggregation isPartOf urn:issn:1759-9954.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Main-chain chiral copoly(2-oxazoline)s".
- aggregation abstract "(Chiral) poly(2-oxazoline)s are regarded as pseudo-polypeptides, however, not much is known about their secondary structure formation. Recently we reported that chiral homopolymers based on R-and S-2-butyl-4-ethyl-2-oxazoline (BuEtOx) monomers form flexible dynamic helices in solution (Soft Matter, 2010, 6, 994-1003) and a chiral crystalline structure in the solid state (Macromolecules, 2010, 43, 4654-4659). In the current work we addressed the chiral structure formation of main-chain chiral copoly(2-oxazoline) s with controlled ratio of S-BuEtOx and R-BuEtOx. No chiral amplification was found in solution or in the solid state, clearly indicating that the polymers adopt a dynamic helical structure that is easily disrupted by incorporation of the second monomer. Nonetheless, the properties of these main-chain chiral copoly(2-oxazoline) s, such as the optical rotation, solubility and crystallinity, can be tuned by controlling the enantiomeric excess (ee).".
- aggregation authorList BK967405.
- aggregation endPage "208".
- aggregation issue "1".
- aggregation startPage "203".
- aggregation volume "2".
- aggregation aggregates 1167871.
- aggregation isDescribedBy 1167851.
- aggregation similarTo c0py00264j.
- aggregation similarTo LU-1167851.