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- aggregation classification "A1".
- aggregation creator B382884.
- aggregation creator person.
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- aggregation date "2011".
- aggregation format "application/pdf".
- aggregation hasFormat 1209382.bibtex.
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- aggregation isPartOf urn:issn:0022-3263.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Synthesis of 3-methoxyazetidines via an aziridine to azetidine rearrangement and theoretical rationalization of the reaction mechanism".
- aggregation abstract "The synthetic utility of N-alkylidene-(2,3-dibromo-2-methylpropyl)amines and N-(2,3-dibromo-2-methylpropylidene)benzylamines was demonstrated by the unexpected synthesis of 3-methoxy-3-methylazetidines upon treatment with sodium borohydride in methanol under reflux through a rare aziridine to azetidine rearrangement. These findings stand in contrast to the known reactivity of the closely related N-alkylidene-(2,3-dibromopropyl)amines, which are easily converted into 2-(bromomethyl)aziridines under the same reaction conditions. A thorough insight into the reaction mechanism was provided by both experimental study and theoretical rationalization.".
- aggregation authorList BK691997.
- aggregation endPage "2167".
- aggregation issue "7".
- aggregation startPage "2157".
- aggregation volume "76".
- aggregation aggregates 4133467.
- aggregation aggregates 4133468.
- aggregation isDescribedBy 1209382.
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