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- aggregation classification "A1".
- aggregation creator B605720.
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- aggregation date "2011".
- aggregation format "application/pdf".
- aggregation hasFormat 1972626.bibtex.
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- aggregation isPartOf urn:issn:0947-6539.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "On the determination of the stereochemistry of semisynthetic natural product analogues using chiroptical spectroscopy: desulfurization of epidithiodioxopiperazine fungal metabolites".
- aggregation abstract "Isolation and semisynthetic modification of the fungal metabolite chaetocin gave access to a desulfurized analogue of this natural product. Detailed chiroptical studies, comparing experimentally obtained optical rotation values, electronic circular dichroism spectra, and vibrational circular dichroism spectra to computationally simulated ones, reveal the desulfurization of chaetocin to unambiguously proceed with retention of configuration. Consideration of the plausible mechanisms for this process highlighted inconsistencies in the stereochemical assignment of related molecules in the literature. This in turn allowed the stereochemical reassignment of the natural product analogue dethiodehydrogliotoxin.".
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- aggregation endPage "11875".
- aggregation issue "42".
- aggregation startPage "11868".
- aggregation volume "17".
- aggregation aggregates 4133850.
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- aggregation similarTo chem.201101129.
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