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- aggregation classification "A1".
- aggregation creator B763916.
- aggregation creator B763917.
- aggregation creator B763918.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2012".
- aggregation format "application/pdf".
- aggregation hasFormat 2914246.bibtex.
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- aggregation isPartOf urn:issn:1463-9076.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Vibrational circular dichroism versus optical rotation dispersion and electronic circular dichroism for diastereomers: the stereochemistry of 3-(1'-hydroxyethyl)-1-(3'-phenylpropanoyl)-azetidin-2-one".
- aggregation abstract "The absolute configuration of a relatively large and conformationally flexible chiral compound, 3-(1 '-hydroxyethyl)-1-(3 '-phenylpropanoyl)-azetidin-2-one, is determined using Vibrational Circular Dichroism (VCD) spectroscopy, Optical Rotation Dispersion (ORD) and Electronic Circular Dichroism (ECD). To that end a state of the art experimental VCD spectrum is compared to a theoretical spectrum and the absolute configuration is assigned. ORD and ECD are also used in the assignment to investigate the complementarity of the three techniques. VCD spectroscopy is found to have important advantages over ORD and ECD for diastereomers. The concept of robust modes is applied to this conformationally flexible molecule, showing that its use is limited for such large and flexible molecules.".
- aggregation authorList BK1132570.
- aggregation endPage "8571".
- aggregation issue "24".
- aggregation startPage "8562".
- aggregation volume "14".
- aggregation aggregates 2914291.
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- aggregation similarTo c2cp40617a.
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