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- aggregation classification "A1".
- aggregation creator B435035.
- aggregation creator B435036.
- aggregation creator B435037.
- aggregation creator B435038.
- aggregation creator B435039.
- aggregation creator B435040.
- aggregation creator person.
- aggregation date "2012".
- aggregation hasFormat 2970632.bibtex.
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- aggregation hasFormat 2970632.doc.
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- aggregation hasFormat 2970632.yaml.
- aggregation isPartOf urn:issn:1463-9076.
- aggregation language "eng".
- aggregation subject "Physics and Astronomy".
- aggregation title "High current density electrodeposition from silver complex ionic liquids".
- aggregation abstract "Liquid metal salts are electrolytes with the highest possible metal concentration for electrodeposition, because the metal ion is an integral part of the solvent. This paper introduces the new ionic silver complexes [Ag(MeCN)(4)](2)[Ag(Tf2N)(3)], [Ag(MeCN)][Tf2N] and [Ag(EtIm)(2)][Tf2N], where MeCN stands for acetonitrile, EtIm for 1-ethylimidazole and Tf2N is bis(trifluoromethylsulfonyl)imide. These complexes have been characterized by differential scanning calorimetry, single crystal X-ray crystallography, thermogravimetrical analysis, Raman spectroscopy and cyclic voltammetry. [Ag(MeCN)(4)](2)[Ag(Tf2N)(3)] is a room temperature ionic liquid. Smooth silver layers of good quality could be deposited from it, at current densities of up to 25 A dm(-2) in unstirred solutions. [Ag(EtIm)(2)][Tf2N] melts at 65 degrees C and can be used as an electrolyte for silver deposition above this temperature. [Ag(MeCN)][Tf2N] has a melting point that is too high to be useful in electrodeposition. Addition of thiourea or 1H-benzotriazole to the electrolyte decreased the surface roughness of the silver coatings. The morphology of the metal layers was investigated by atomic force microscopy (AFM). Adsorption of 1H-benzotriazole on the silver metal surface has been proven by Raman spectroscopy. This work shows the usefulness of additives in improving the quality of metal films electrodeposited from ionic liquids.".
- aggregation authorList BK758046.
- aggregation endPage "1715".
- aggregation issue "5".
- aggregation startPage "1706".
- aggregation volume "14".
- aggregation isDescribedBy 2970632.
- aggregation similarTo c2cp22987k.
- aggregation similarTo LU-2970632.