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- aggregation classification "A1".
- aggregation creator B355453.
- aggregation creator B355454.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2012".
- aggregation format "application/pdf".
- aggregation hasFormat 2973409.bibtex.
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- aggregation isPartOf urn:issn:0276-7333.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Striking a compromise: polar functional group tolerance versus insertion barrier height for olefin polymerization catalysts".
- aggregation abstract "The coordination-insertion random copolymerization of polar and nonpolar olefins holds great potential for the design of new polymers with targeted properties. However, examples of catalysts capable of such polymerization still remain scarce, the majority of which are based on Pd-II and some also on Ni-II. So far, the apparent superiority of Pd-II has not been rationalized. In this work, the catalytic potential of a broad range of transition metals is assessed by investigating their polar functional group tolerance and insertion barrier heights far realistic and comparable complexes. Multivariate regression models suggest that the pi-back-donation ability of the metal plays an important role in both the polar functional group tolerance and the insertion barrier height. Specifically, the polar functional group tolerance and insertion barrier height were found to correlate positively, indicating that a compromise must be struck. Pd-II seems to strike this balance optimally, thus explaining its prominent position as a transition-metal catalyst for copolymerization of polar with nonpolar olefins.".
- aggregation authorList BK655195.
- aggregation endPage "6031".
- aggregation issue "17".
- aggregation startPage "6022".
- aggregation volume "31".
- aggregation aggregates 2973678.
- aggregation aggregates 2975035.
- aggregation aggregates 3035769.
- aggregation isDescribedBy 2973409.
- aggregation similarTo om3000828.
- aggregation similarTo LU-2973409.