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- aggregation classification "A1".
- aggregation creator B583590.
- aggregation creator B583591.
- aggregation creator B583592.
- aggregation creator B583593.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2012".
- aggregation format "application/pdf".
- aggregation hasFormat 3040441.bibtex.
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- aggregation isPartOf urn:issn:0947-6539.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Solvent-catalyzed ring-chain-ring tautomerization in axially chiral compounds".
- aggregation abstract "The mechanism of ring-chain-ring tautomerization and the prominent effect of the solvent environment have been computationally investigated in an effort to explain the enantiomeric interconversion observed in 2-oxazolidinone derivatives, heterocyclic analogues of biphenyl atropisomers, which were isolated as single stable enantiomers and have the potential to be used as axially chiral catalysts. This study has shed light on the identity of the intermediate species involved in the ring-chain-ring tautomerization process as well as the catalytic effect of polar protic solvents. These mechanistic details will prove very useful in predicting and understanding ring-chain tautomeric equilibria in similar heterocyclic systems and will further enable experimentalists to devise appropriate experimental conditions in which axially chiral catalysts remain stable as single enantiomers.".
- aggregation authorList BK936265.
- aggregation endPage "12732".
- aggregation issue "40".
- aggregation startPage "12725".
- aggregation volume "18".
- aggregation aggregates 3040450.
- aggregation isDescribedBy 3040441.
- aggregation similarTo chem.201200363.
- aggregation similarTo LU-3040441.