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- aggregation classification "A1".
- aggregation creator B224582.
- aggregation creator B224583.
- aggregation creator B224584.
- aggregation creator person.
- aggregation date "2012".
- aggregation format "application/pdf".
- aggregation hasFormat 3164432.bibtex.
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- aggregation isPartOf urn:issn:0021-8561.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Flavonoid deactivation of excited state flavins: reaction monitoring by mass spectrometry".
- aggregation abstract "Flavin mononucleotide (FMN, as a B-2 vitamin model) was shown to induce dimerization of flavonoids (flavanone, apigenin, naringenin, eriodictyol, taxifolin, catechin, kaempferol, luteolin, quercetin, rutin, and seven smaller model phenols studied) as the major photoreaction, when aqueous solutions were exposed to visible light using a new, real-time electrospray ionization mass-spectrometric (ESI-MS) technique supported by LC-MS and MS2 analysis. Electrophilic intermediates such as transient radical cations, o-quinones, and p-quinone methide were proposed to be involved in the coupling process. The C-3-OH in flavon-3-ols gave rise to atypical compounds such as a depside or a dioxane-linked dimer. Flavonoid dimers, formed in vegetal extracts added to food during storage in light and for which structures are proprosed based on MS and MS2, may affect colloidal stability, color, astringency, and antioxidative capacity.".
- aggregation authorList BK491730.
- aggregation endPage "9272".
- aggregation issue "36".
- aggregation startPage "9261".
- aggregation volume "60".
- aggregation aggregates 3164552.
- aggregation isDescribedBy 3164432.
- aggregation similarTo jf301823h.
- aggregation similarTo LU-3164432.