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- aggregation classification "A1".
- aggregation creator person.
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- aggregation date "2013".
- aggregation format "application/pdf".
- aggregation hasFormat 3182804.bibtex.
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- aggregation isPartOf urn:issn:0024-9297.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Technology and Engineering".
- aggregation title "Kinetic modeling of radical thiol-ene chemistry for macromolecular design: importance of side reactions and diffusional limitations".
- aggregation abstract "The radical thiol-ene coupling of thiol-functionalized polystyrene (PS-SH) with dodecyl vinyl ether (DVE) and the polystyrene-b-poly(vinyl acetate) (PS-b-PVAc) polymer-polymer conjugation using 2,2-dimethoxy-2-phenylacetophenone (DMPA) as photoinitiator are modeled to assess the importance of diffusional limitations and side reactions. Intrinsic chemical rate coefficients are determined based on a kinetic study of the coupling of benzyl thiol (BT) and DVE. The addition and transfer reactions are chemically controlled, whereas diffusional limitations on termination slightly increase the coupling efficiency. Termination by recombination of carbon-centered radicals and addition of DMPA derived radicals to DVE are shown to be mainly responsible for the reduced coupling efficiency in case polymeric species are involved. The obtained results confirm the idea to disregard radical thiol-ene chemistry as a true member of the family of "click" chemistry techniques for polymer-polymer conjugation and show that the initial coupling efficiency. conditions have a significant impact on the".
- aggregation authorList BK1129834.
- aggregation endPage "1742".
- aggregation issue "5".
- aggregation startPage "1732".
- aggregation volume "46".
- aggregation aggregates 3182841.
- aggregation isDescribedBy 3182804.
- aggregation similarTo ma302619k.
- aggregation similarTo LU-3182804.