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- aggregation classification "A1".
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2008".
- aggregation format "application/pdf".
- aggregation hasFormat 418218.bibtex.
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- aggregation isPartOf urn:issn:0892-7022.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Using elementary reactions to model growth processes of polyaromatic hydrocarbons under pyrolysis conditions of light feedstocks".
- aggregation abstract "Density functional theory results are presented for elementary steps leading to coke growth within a steam cracking unit. The discussed pathway starts from toluene and ultimately, 1-methylnaphthalene is formed. In order to find the rate determining step for coke formation, the pseudo first-order rate coefficients of the various steps are compared taking into account the concentrations of diverse coke precursors. The influence of the polyaromatic environment is studied for a large set of methylated polycyclic aromatic molecules, by means of carbon-hydrogen bond dissociation enthalpy values. Subsequent hydrogen abstraction reactions at the methylated polyaromatics, by a methyl radical, are also examined. The abstraction is found to preferentially occur at the larger systems and is in general faster compared to abstractions at the analogous non-methylated species.".
- aggregation authorList BK756502.
- aggregation endPage "199".
- aggregation issue "2".
- aggregation startPage "193".
- aggregation volume "34".
- aggregation aggregates 766500.
- aggregation isDescribedBy 418218.
- aggregation similarTo 08927020801930588.
- aggregation similarTo LU-418218.