Matches in UGent Biblio for { <https://biblio.ugent.be/publication/4443120#aggregation> ?p ?o. }
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- aggregation classification "A1".
- aggregation creator B676001.
- aggregation creator B676002.
- aggregation creator B676003.
- aggregation creator B676004.
- aggregation creator B676005.
- aggregation creator B676006.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2014".
- aggregation format "application/pdf".
- aggregation hasFormat 4443120.bibtex.
- aggregation hasFormat 4443120.csv.
- aggregation hasFormat 4443120.dc.
- aggregation hasFormat 4443120.didl.
- aggregation hasFormat 4443120.doc.
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- aggregation hasFormat 4443120.yaml.
- aggregation isPartOf urn:issn:1433-7851.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Enantioselective assembly of a ruthenium(II) polypyridyl complex into a double helix".
- aggregation abstract "Evolution can increase the complexity of matter by self-organization into helical architectures, the best example being the DNA double helix. One common aspect, apparently shared by most of these architectures, is the presence of covalent bonds within the helix backbone. Here, we report the unprecedented crystal structures of a metal complex that self-organizes into a continuous double helical structure, assembled by non-covalent building blocks. Built up solely by weak stacking interactions, this alternating tread stairs-like double helical assembly mimics the DNA double helix structure. Starting from a racemic mixture in aqueous solution, the ruthenium(II) polypyridyl complex forms two polymorphic structures of a left-handed double helical assembly of only the Lambda-enantiomer. The stacking of the helices is different in both polymorphs: a crossed woodpile structure versus a parallel columnar stacking.".
- aggregation authorList BK1038351.
- aggregation endPage "8962".
- aggregation issue "34".
- aggregation startPage "8959".
- aggregation volume "53".
- aggregation aggregates 4443123.
- aggregation isDescribedBy 4443120.
- aggregation similarTo anie.201404496.
- aggregation similarTo LU-4443120.