Matches in UGent Biblio for { <https://biblio.ugent.be/publication/484161#aggregation> ?p ?o. }
Showing items 1 to 34 of
34
with 100 items per page.
- aggregation classification "A1".
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2009".
- aggregation format "application/pdf".
- aggregation hasFormat 484161.bibtex.
- aggregation hasFormat 484161.csv.
- aggregation hasFormat 484161.dc.
- aggregation hasFormat 484161.didl.
- aggregation hasFormat 484161.doc.
- aggregation hasFormat 484161.json.
- aggregation hasFormat 484161.mets.
- aggregation hasFormat 484161.mods.
- aggregation hasFormat 484161.rdf.
- aggregation hasFormat 484161.ris.
- aggregation hasFormat 484161.txt.
- aggregation hasFormat 484161.xls.
- aggregation hasFormat 484161.yaml.
- aggregation isPartOf urn:issn:1463-9076.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Theoretical evaluation of zeolite confinement effects on the reactivity of bulky intermediates".
- aggregation abstract "Zeolites provide a unique setting for heterogeneous Bronsted acid catalysis, because the effects of the surrounding framework on fundamental reaction kinetics go well beyond what would be expected for a mere reaction. ask. This aspect becomes very pronounced when bulky molecules form key intermediates for the reaction under study, which is exactly when the interaction between the framework and the intermediate is maximal. We will use the example of methanol-to-olefin conversion (MTO), and, more specifically, the constant interplay between the inorganic host framework and the organic hydrocarbon pool co-catalyst, to illustrate how zeolite confinement directly influences catalytic reaction rates. Theoretical calculations are used to isolate and quantify these specific effects, with the main focus on methylbenzenes in ZSM-5, as the archetypical MTO catalyst. This review intends to give an overview of recent theoretical insights, which have proven to provide an ideal complementary tool to experimental investigations. In addition, we will also introduce the role of zeolite breathing in activating a catalytic cycle.".
- aggregation authorList BK730169.
- aggregation endPage "5226".
- aggregation issue "26".
- aggregation startPage "5222".
- aggregation volume "11".
- aggregation aggregates 719931.
- aggregation isDescribedBy 484161.
- aggregation similarTo b902364j.
- aggregation similarTo LU-484161.