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- aggregation classification "A1".
- aggregation creator B444787.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2008".
- aggregation hasFormat 524419.bibtex.
- aggregation hasFormat 524419.csv.
- aggregation hasFormat 524419.dc.
- aggregation hasFormat 524419.didl.
- aggregation hasFormat 524419.doc.
- aggregation hasFormat 524419.json.
- aggregation hasFormat 524419.mets.
- aggregation hasFormat 524419.mods.
- aggregation hasFormat 524419.rdf.
- aggregation hasFormat 524419.ris.
- aggregation hasFormat 524419.txt.
- aggregation hasFormat 524419.xls.
- aggregation hasFormat 524419.yaml.
- aggregation isPartOf urn:issn:1477-0520.
- aggregation language "eng".
- aggregation subject "Chemistry".
- aggregation title "A new entry into cis-3-amino-2-methylpyrrolidines via ring expansion of 2-(2-hydroxyethyl)-3-methylaziridines".
- aggregation abstract "3-Amino-2-methylpyrrolidines were prepared via a novel protocol, involving the reductive ring closure and O-deprotection of gamma-acetoxy-alpha-chloroketimines towards 2-(2-hydroxyethyl)-3-methylaziridines, followed by ring expansion of the latter into 3-bromopyrrolidines via intermediate bicyclic aziridinium salts and consecutive nucleophilic displacement of the bromo atom by azide towards 3-azidopyrrolidines. A final reduction of the azide moiety furnished 3-amino-2-methylpyrrolidines in high yields. Thus, a new formal synthesis of the antipsychotic emonapride was developed through preparation and further aroylation of cis-3-amino-1-benzyl-2-methylpyrrolidine.".
- aggregation authorList BK776590.
- aggregation endPage "141".
- aggregation issue "1".
- aggregation startPage "135".
- aggregation volume "7".
- aggregation isDescribedBy 524419.
- aggregation similarTo b816617j.
- aggregation similarTo LU-524419.