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- aggregation classification "B2".
- aggregation creator B927456.
- aggregation creator person.
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- aggregation creator person.
- aggregation creator person.
- aggregation date "2009".
- aggregation hasFormat 528856.bibtex.
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- aggregation hasFormat 528856.dc.
- aggregation hasFormat 528856.didl.
- aggregation hasFormat 528856.doc.
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- aggregation language "eng".
- aggregation publisher "Kluwer Academic".
- aggregation subject "Chemistry".
- aggregation title "From novel block-like copolymers to reactive nanoparticles: ATRP and “click” chemistry as synthetic tools".
- aggregation abstract "In this chapter, we report on the synthesis and characterization of well-defined amphiphilic block copolymers, ‘block-like’ copolymers and star copolymers composed of poly(isobornyl acrylate) (PiBA) and poly(acrylic acid) (PAA) by ATRP. As PiBA polymers exhibit interesting physical characteristics, we report first a detailed study of the homopolymerization of iBA. The precursor monomers 1-ethoxyethyl acrylate as well as tert-butyl acrylate have been used to synthesize the precursor polymers for the PiBA-co-PAA block copolymers. Furthermore, a combination of ATRP and ‘click’ chemistry was used to prepare block and graft copolymers using a modular approach. The PiBA-PAA block and ‘block-like’ copolymers were investigated as pigment stabilizers for aqueous pigment dispersions. In a second part of the research, well-defined PiBA star copolymers were prepared, and reactive nanoparticles were obtained by end group modification of the PiBA star polymers with reactive moieties. Finally, the control of the visco-elastic properties by the incorporation of these nanoparticles in an acrylate polymer matrix was investigated.".
- aggregation authorList BK1310096.
- aggregation isDescribedBy 528856.
- aggregation similarTo LU-528856.