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- aggregation classification "A1".
- aggregation creator person.
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- aggregation date "2014".
- aggregation format "application/pdf".
- aggregation hasFormat 5674303.bibtex.
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- aggregation isPartOf urn:issn:0888-5885.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Technology and Engineering".
- aggregation title "ICAR ATRP for estimation of intrinsic macro-activation/deactivation Arrhenius parameters under polymerization condition".
- aggregation abstract "The potential of Initiators for Continuous Activator Regeneration Atom Transfer Radical Polymerization (ICAR ATRP) to determine reliable Arrhenius parameters for ATRP activation/deactivation of macrospecies is illustrated using styrene as monomer and CuBr2/TPMA (TPMA: tris(2-pyridylmethyl)amine) as deactivator. Regression is based on an extensive set of experimental data limited to conversions below 0.50 to avoid the interference of diffusional limitations on the activation/deactivation process and recorded at temperatures below 90 degrees C to avoid the influence of thermal self-initiation. Diffusional limitations on termination are accounted for based on literature data. The activation energy for the activation and deactivation reaction involving macrospecies are respectively 29 and 1.7 kJ mol(-1). The corresponding pre-exponentional factors are 6.9 x 10(5) and 1.8 x 10(7) L mol(-1) s(-1). At 70 degrees C, the corresponding rate coefficients amount to 2.2 x 10 and 9.9 x 10(6) L mol(-1) s(-1) confirming the relatively high activity of CuBr/TPMA as ATRP catalyst.".
- aggregation authorList BK1407414.
- aggregation endPage "9685".
- aggregation issue "23".
- aggregation startPage "9674".
- aggregation volume "53".
- aggregation aggregates 5674356.
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