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- aggregation classification "A1".
- aggregation creator B982569.
- aggregation creator B982570.
- aggregation creator B982571.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2014".
- aggregation format "application/pdf".
- aggregation hasFormat 5701322.bibtex.
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- aggregation isPartOf urn:issn:1932-7447.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Vulcanized ethene-PMO: a new strategy to create ultrastable support materials and adsorbents".
- aggregation abstract "A periodic mesoporous organosilica (PMO) functionalized with sulfur units between the organic bridges has been successfully synthesized by a postsynthetic cold vulcanization treatment performed on an ethenylene-bridged PMO material (ethene-PMO). The results of X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and nitrogen adsorption/desorption porosimetry show that the resultant materials have well-ordered hexagonal mesoporous structures with narrow pore size distributions. Moreover, C-13 CP/MAS NMR, Si-29 MAS NMR, X-ray photoelectron spectroscopy (XPS), and elemental analysis prove the cross-linking between the organic moieties through additional sulfur bridges. Besides the incorporation of a new functionality to this PMO, the vulcanization treatment, reminiscent of that applied to rubber, improves the thermal and hydrothermal stabilities of the material. The vulcanized materials were employed as mercury adsorbents able to be reused without loss of their capacity in repetitive adsorption tests.".
- aggregation authorList BK1381854.
- aggregation endPage "17869".
- aggregation issue "31".
- aggregation startPage "17862".
- aggregation volume "118".
- aggregation aggregates 5701329.
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- aggregation similarTo jp5059726.
- aggregation similarTo LU-5701322.