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- aggregation classification "A1".
- aggregation creator B927499.
- aggregation creator B927500.
- aggregation creator B927501.
- aggregation creator B927502.
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- aggregation date "2014".
- aggregation format "application/pdf".
- aggregation hasFormat 5712490.bibtex.
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- aggregation isPartOf urn:issn:1861-4728.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Nucleophile-dependent regio- and stereoselective ring opening of 1-azoniabicyclo[3.1.0]hexane tosylate".
- aggregation abstract "1-[(1R)-(1-Phenylethyl)]-1-azoniabicyclo[3.1.0]hexane tosylate was generated as a stable bicyclic aziridinium salt from the corresponding 2-(3-hydroxypropyl)aziridine upon reaction with p-toluenesulfonyl anhydride. This bicyclic aziridinium ion was then treated with various nucleophiles including halides, azide, acetate, and cyanide in CH3CN to afford either piperidines or pyrrolidines through regio- and stereoselective ring opening, mediated by the characteristics of the applied nucleophile. On the basis of DFT calculations, ring-opening reactions under thermodynamic control yield piperidines, whereas reactions under kinetic control can yield both piperidines and pyrrolidines depending on the activation energies for both pathways.".
- aggregation authorList BK1310288.
- aggregation endPage "1067".
- aggregation issue "4".
- aggregation startPage "1060".
- aggregation volume "9".
- aggregation aggregates 5712545.
- aggregation isDescribedBy 5712490.
- aggregation similarTo asia.201301551.
- aggregation similarTo LU-5712490.