Matches in UGent Biblio for { <https://biblio.ugent.be/publication/5837642#aggregation> ?p ?o. }
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- aggregation classification "A1".
- aggregation creator B919777.
- aggregation creator B919778.
- aggregation creator person.
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- aggregation date "2015".
- aggregation format "application/pdf".
- aggregation hasFormat 5837642.bibtex.
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- aggregation isPartOf urn:issn:1759-9954.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Accelerated living cationic ring-opening polymerization of a methyl ester functionalized 2-oxazoline monomer".
- aggregation abstract "Kinetic studies on the homo-and copolymerization of 2-methoxycarboxyethyl- 2-oxazoline (MestOx) with 2-methyl-2-oxazoline (MeOx) and 2-ethyl-2-oxazoline (EtOx) were performed. For the homopolymerisation of MestOx an increased propagation rate constant was observed compared to MeOx and EtOx while the copolymerization of MestOx with MeOx or EtOx unexpectedly revealed slower incorporation of MestOx. Density functional theory (DFT) calculations show that nearby MestOx residues in the living chain can activate both the oxazolinium chain end and the attacking monomer, stabilizing the propagation transition state, leading to faster homopolymerisation of MestOx. These effects also accelerate incorporation of both monomers in the copolymerisations. However, since MeOx is shown to be more nucleophilic than MestOx, the incorporation order is reversed in the copolymerisations.".
- aggregation authorList BK1301655.
- aggregation endPage "518".
- aggregation issue "4".
- aggregation startPage "514".
- aggregation volume "6".
- aggregation aggregates 5837664.
- aggregation isDescribedBy 5837642.
- aggregation similarTo c4py01373e.
- aggregation similarTo LU-5837642.