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- aggregation classification "P1".
- aggregation creator B48912.
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- aggregation date "2010".
- aggregation format "application/pdf".
- aggregation hasFormat 784804.bibtex.
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- aggregation isPartOf urn:isbn:9789048134311.
- aggregation isPartOf urn:issn:1871-4641.
- aggregation language "eng".
- aggregation publisher "Springer".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Ruthenium–indenylidene complexes bearing saturated N-heterocyclic carbenes: synthesis and application in ring-closing metathesis reactions".
- aggregation abstract "The synthesis of complexes of the general formula Cl2Ru(SIMes)(L)(3-phenylinden-1-ylidene), 3a (L = PCy3), 3b (L = PPh3), 3c (L = py) and Cl2Ru(SIMe)(L)(3-phenylinden-1-ylidene), 4c (L = PCy3), 4b (L = PPh3), 4c (L = py) from commercially available Cl2Ru(PR3)(2)(3-phenylinden-1-ylidene), 2a (R = Cy), 2b (R = Ph), is reported, and the summed complexes proved to be useful catalysts for various ring-closing metathesis reactions. The catalytic data reported furthermore demonstrate that the substitution pattern of the N-aryl group has a definite influence on the activity of the second generation indenylidene catalysts for a given metathesis reaction, i.e. catalysts containing the SIMe-ligand showed improved initiation compared to the more robust SIMes substituted catalysts. A strong temperature effect was observed on all of the reactions tested. It is shown that complexes containing the SIMe-ligand display higher initiation efficiency then their corresponding SIMes analogues.".
- aggregation authorList BK124244.
- aggregation endPage "38".
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- aggregation aggregates 1190698.
- aggregation isDescribedBy 784804.
- aggregation similarTo 978-90-481-3433-5_3.
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