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- aggregation classification "A1".
- aggregation creator B329771.
- aggregation creator B329772.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2010".
- aggregation format "application/pdf".
- aggregation hasFormat 852218.bibtex.
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- aggregation hasFormat 852218.doc.
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- aggregation hasFormat 852218.yaml.
- aggregation isPartOf urn:issn:0022-3263.
- aggregation language "eng".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Heteroaryl cross-coupling as an entry toward the synthesis of lavendamycin analogues: a model study".
- aggregation abstract "ABC analogues of the antitumor antibiotic lavendamycin, which contain the key metal chelation site and redox-active quinone unit essential for biological activity, were prepared via the palladium(0)-catalyzed cross-coupling reaction of various 2-haloheteroatomics with 2-stannylated pyridines and quinolines. Using the Stille reaction, 2-bromo substituted quinolines and 1-bromoisoquinolines were found to undergo efficient coupling with 2-pyridinylstannanes to provide unsymmetrical heterobiaryl derivatives. While the Stille reaction using the reverse coupling partners (i.e., 2-quinolinylstannanes and haloheteroaromatics) had not received much attention in the literature, we found that this alternative coupling reaction efficiently provided several new heterobiaryl derivatives. The gold-catalyzed intramolecular cycloisomerization of N-(prop-2-ynyl)-1H-indole-2-carboxamide smoothly afforded a beta-carbolinone derivative that was subsequently used for it Pd(0)-catalyzed cross-coupling directed toward the synthesis of lavendamycin analogues.".
- aggregation authorList BK622035.
- aggregation endPage "433".
- aggregation issue "2".
- aggregation startPage "424".
- aggregation volume "75".
- aggregation aggregates 1259582.
- aggregation aggregates 980102.
- aggregation isDescribedBy 852218.
- aggregation similarTo jo902287t.
- aggregation similarTo LU-852218.