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- aggregation classification "C3".
- aggregation creator B119565.
- aggregation creator B119566.
- aggregation creator B119567.
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- aggregation date "2010".
- aggregation format "application/pdf".
- aggregation hasFormat 873132.bibtex.
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- aggregation language "eng".
- aggregation rights "I have retained and own the full copyright for this publication".
- aggregation subject "Science General".
- aggregation title "Insights on the adsorption behavior of aromatics in MIL-47 and MIL-53 from a theoretical perspective".
- aggregation abstract "Recently, the spectrum of nanoporous materials like zeolites and zeotype structures has been further expanded through the discovery of a new class of hybrid porous solids [1, 2]. Those materials, nowadays also known as metal organic frameworks or MOFs, consist of both inorganic and organic moieties. Certain MOFs exhibit a very interesting adsorption and even catalytic behavior. Within this contribution, we will mainly focus on adsorption and separation of aromatic species in MIL-47 and MIL-53 [3, 4, 5]. Some of the presenting authors reported for first time on the successful use of MOFs as selective adsorbents for the extremely difficult and industrially relevant separations of para-xylene versus meta-xylene and para-xylene versus ethylbenzene [3]. Their study focuses on the MIL-47, which was first synthesized by Barthelet [4]. This separation behavior of MIL-47 could be better understood with adsorption studies [3, 5]. The packing of each C8-pair will be discussed on the basis of the interactions between those two aromatic compounds and MIL-47 [3]. In order to unravel the interaction between the guest molecules and the lattice, periodic Density Functional Theory calculations have been conducted. The DFT calculations were corrected for dispersion interaction [6] to include the long-range attractive forces. It seems that pi-pi stacking energies between pairs of aromatics but also with the walls of the MOF are crucial for the packing behavior in the pores.".
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