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- aggregation classification "A1".
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation creator person.
- aggregation date "2010".
- aggregation hasFormat 954649.bibtex.
- aggregation hasFormat 954649.csv.
- aggregation hasFormat 954649.dc.
- aggregation hasFormat 954649.didl.
- aggregation hasFormat 954649.doc.
- aggregation hasFormat 954649.json.
- aggregation hasFormat 954649.mets.
- aggregation hasFormat 954649.mods.
- aggregation hasFormat 954649.rdf.
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- aggregation hasFormat 954649.txt.
- aggregation hasFormat 954649.xls.
- aggregation hasFormat 954649.yaml.
- aggregation isPartOf urn:issn:1477-0520.
- aggregation language "eng".
- aggregation subject "Chemistry".
- aggregation title "Stereoselective synthesis of trans- and cis-2-aryl-3-(hydroxymethyl)aziridines through transformation of 4-aryl-3-chloro-β-lactams and study of their ring opening".
- aggregation abstract "trans- and cis-1-Alkyl-4-aryl-3-chloroazetidin-2-ones, prepared through cyclocondensation of chloroketene and the appropriate imines in a diastereoselective way, were transformed into the corresponding non-activated trans- and cis-2-aryl-3-(hydroxymethyl)aziridines via reductive ring contraction using LiAlH4 in Et2O. Furthermore, trans- 2-aryl-3-(hydroxymethyl) aziridines were transformed into 2-amino-3-arylpropan-1-ols and anti-2-amino-3-aryl-3-methoxypropan-1-ols by means of an unprecedented ring opening by LiAlH4 and by MeOH, respectively. cis-2-Aryl-3(hydroxymethyl)aziridines were shown to be highly reluctant to undergo ring opening by LiAlH4 and MeOH under similar reaction conditions.".
- aggregation authorList BK733368.
- aggregation endPage "615".
- aggregation issue "3".
- aggregation startPage "607".
- aggregation volume "8".
- aggregation isDescribedBy 954649.
- aggregation similarTo b919864d.
- aggregation similarTo LU-954649.