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- Achmatowicz_reaction abstract "The Achmatowicz Reaction is an organic synthesis in which a furan is converted to a dihydropyran. In the original publication by Osman Achmatowicz Jr. in 1971 furfuryl alcohol is reacted with bromine in methanol to 2,5-dimethoxy-2,5-dihydrofuran which rearranges to the dihydropyran with dilute sulfuric acid. Additional reaction steps, alcohol protection with methyl orthoformate and boron trifluoride) and ketone reduction with sodium borohydride produce an intermediate from which many monosaccharides can be synthesised.The Achmatowicz reactionThe Achmatowitz protocol has been used in total synthesis for example that of desoxoprosophylline, Pyrenophorin and Bao Gong Teng A. Very recently it has been used in diversity oriented synthesis Achmatowicz Burke 2006and in enantiomeric scaffolding.Achmatowicz Reaction Coombs 2008↑ ↑ ↑ ↑ ↑ ↑ ↑ ↑".
- Achmatowicz_reaction thumbnail The_Achmatowicz_reaction.svg?width=300.
- Achmatowicz_reaction wikiPageID "16161577".
- Achmatowicz_reaction wikiPageRevisionID "541441229".
- Achmatowicz_reaction hasPhotoCollection Achmatowicz_reaction.
- Achmatowicz_reaction subject Category:Name_reactions.
- Achmatowicz_reaction subject Category:Organic_reactions.
- Achmatowicz_reaction type ChemicalProcess113446390.
- Achmatowicz_reaction type ChemicalReaction113447361.
- Achmatowicz_reaction type NameReactions.
- Achmatowicz_reaction type NaturalProcess113518963.
- Achmatowicz_reaction type OrganicReactions.
- Achmatowicz_reaction type PhysicalEntity100001930.
- Achmatowicz_reaction type Process100029677.
- Achmatowicz_reaction comment "The Achmatowicz Reaction is an organic synthesis in which a furan is converted to a dihydropyran. In the original publication by Osman Achmatowicz Jr. in 1971 furfuryl alcohol is reacted with bromine in methanol to 2,5-dimethoxy-2,5-dihydrofuran which rearranges to the dihydropyran with dilute sulfuric acid.".
- Achmatowicz_reaction label "Achmatowicz reaction".
- Achmatowicz_reaction label "Achmatowicz反应".
- Achmatowicz_reaction label "Reacción de Achmatowicz".
- Achmatowicz_reaction label "Reakcja Achmatowicza".
- Achmatowicz_reaction sameAs Reacción_de_Achmatowicz.
- Achmatowicz_reaction sameAs Reaksi_Achmatowicz.
- Achmatowicz_reaction sameAs Reazione_di_Achmatowicz.
- Achmatowicz_reaction sameAs Reakcja_Achmatowicza.
- Achmatowicz_reaction sameAs m.03wbl58.
- Achmatowicz_reaction sameAs Q3493761.
- Achmatowicz_reaction sameAs Q3493761.
- Achmatowicz_reaction sameAs Achmatowicz_reaction.
- Achmatowicz_reaction wasDerivedFrom Achmatowicz_reaction?oldid=541441229.
- Achmatowicz_reaction depiction The_Achmatowicz_reaction.svg.
- Achmatowicz_reaction isPrimaryTopicOf Achmatowicz_reaction.
