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- Carborane abstract "A carborane is a cluster composed of boron, carbon and hydrogen atoms. Like many of the related boranes, these clusters are polyhedra and are similarly classified as closo-, nido-, arachno-, hypho-, etc. based on whether they represent a complete (closo-) polyhedron, or a polyhedron that is missing one (nido-), two (arachno-), or more vertices.Interesting examples of carboranes are the extremely stable icosahedral closo-carboranes. These boron-rich clusters exhibit unique organomimetic properties with chemical reactivity matching classical organic molecules, yet structurally similar to metal-based inorganic and organometallic speciesA prominent example is the charge-neutral C2B10H12 or o-carborane with the prefix o derived from ortho, which has been explored for use in a wide range of applications from heat-resistant polymers to medical applications. The electronic structure of these compounds is best described by Wade-Mingos rules for cluster molecules. At 420 °C o-carborane converts to the meta isomer. In comparison, benzene requires a >1000 °C to induce skeletal rearrangement. Like arenes, carboranes also undergo electrophilic aromatic substitution. Another important carborane is carborane acid, a chlorinated superacid H(CHB11Cl11), which has an anion structure shown at right.".
- Carborane thumbnail O-carborane-3D-balls.png?width=300.
- Carborane wikiPageExternalLink o-carboranemsds.pdf.
- Carborane wikiPageExternalLink strong_gentle.html.
- Carborane wikiPageID "1206475".
- Carborane wikiPageRevisionID "596049440".
- Carborane hasPhotoCollection Carborane.
- Carborane subject Category:Cluster_chemistry.
- Carborane subject Category:Organoboron_compounds.
- Carborane subject Category:Superacids.
- Carborane type Abstraction100002137.
- Carborane type Cognition100023271.
- Carborane type Compound105870180.
- Carborane type Concept105835747.
- Carborane type Content105809192.
- Carborane type Idea105833840.
- Carborane type OrganoboronCompounds.
- Carborane type PsychologicalFeature100023100.
- Carborane type Whole105869584.
- Carborane comment "A carborane is a cluster composed of boron, carbon and hydrogen atoms. Like many of the related boranes, these clusters are polyhedra and are similarly classified as closo-, nido-, arachno-, hypho-, etc. based on whether they represent a complete (closo-) polyhedron, or a polyhedron that is missing one (nido-), two (arachno-), or more vertices.Interesting examples of carboranes are the extremely stable icosahedral closo-carboranes.".
- Carborane label "Carboraan".
- Carborane label "Carborane".
- Carborane label "Carborane".
- Carborane label "Carborane".
- Carborane label "Carborani".
- Carborane label "Carborano".
- Carborane label "Carborano".
- Carborane label "Карбораны".
- Carborane label "カルボラン".
- Carborane label "碳硼烷".
- Carborane sameAs Carborane.
- Carborane sameAs Carborano.
- Carborane sameAs Carborane.
- Carborane sameAs Carborani.
- Carborane sameAs カルボラン.
- Carborane sameAs 카보레인.
- Carborane sameAs Carboraan.
- Carborane sameAs Carborano.
- Carborane sameAs m.04h7_m.
- Carborane sameAs Q413945.
- Carborane sameAs Q413945.
- Carborane sameAs Carborane.
- Carborane wasDerivedFrom Carborane?oldid=596049440.
- Carborane depiction O-carborane-3D-balls.png.
- Carborane isPrimaryTopicOf Carborane.
