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- Decarboxylative_cross-coupling abstract "Decarboxylative cross coupling reactions are chemical reactions in which a stable, substituted carboxylic acid is reacted with a halide (R–X, R=aryl, alkyl, etc.) in the presence of a metal catalyst, base and oxidant to form a new carbon-carbon bond (with loss of carbon dioxide).A significant advantage of this reaction is that it uses relatively inexpensive carboxylic acids (or their salts) and is far less air and moisture sensitive in comparison to typical cross-coupling organometallic reagents. Furthermore, the carboxylic acid moiety is a common feature of natural products and can also be prepared by relatively benign air oxidations. Additional benefits include the broad tolerance of functional groups, as well as the capacity to avoid the use of strong bases. An important elementary step in this reaction is protodecarboxylation or metallation to first convert the C–COOH bond to a C–H or C–M bond respectively.".
- Decarboxylative_cross-coupling thumbnail Decarboxylative_Cross_Coupling_General_Reaction_Scheme.png?width=300.
- Decarboxylative_cross-coupling wikiPageID "36929630".
- Decarboxylative_cross-coupling wikiPageRevisionID "582951719".
- Decarboxylative_cross-coupling hasPhotoCollection Decarboxylative_cross-coupling.
- Decarboxylative_cross-coupling subject Category:Chemical_reactions.
- Decarboxylative_cross-coupling subject Category:Chemistry.
- Decarboxylative_cross-coupling comment "Decarboxylative cross coupling reactions are chemical reactions in which a stable, substituted carboxylic acid is reacted with a halide (R–X, R=aryl, alkyl, etc.) in the presence of a metal catalyst, base and oxidant to form a new carbon-carbon bond (with loss of carbon dioxide).A significant advantage of this reaction is that it uses relatively inexpensive carboxylic acids (or their salts) and is far less air and moisture sensitive in comparison to typical cross-coupling organometallic reagents. ".
- Decarboxylative_cross-coupling label "Decarboxylative cross-coupling".
- Decarboxylative_cross-coupling sameAs m.0pd9p6x.
- Decarboxylative_cross-coupling sameAs Q5248748.
- Decarboxylative_cross-coupling sameAs Q5248748.
- Decarboxylative_cross-coupling wasDerivedFrom Decarboxylative_cross-coupling?oldid=582951719.
- Decarboxylative_cross-coupling depiction Decarboxylative_Cross_Coupling_General_Reaction_Scheme.png.
- Decarboxylative_cross-coupling isPrimaryTopicOf Decarboxylative_cross-coupling.
