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- Degenerative_chain_transfer abstract "In polymer chemistry, degenerative chain transfer (also called degenerate chain transfer) is a process that can occur in a radical polymerization whereby reactivity of active centres are changed, hence significantly influencing the molecular weight distribution of the resulting product.In chain polymerization processes it is observed that during the chemical reactions an active centre on a growing chain is transferred from a growing macromolecule - P• - or oligomer to another molecule (transfer agent XR) or to another site on the same molecule.P• + XR → PX + R•This transfer involves termination of the initially growing chain to the completed macromolecule PX, where X denotes one end-group of the macromolecule. The example shows that the growing macromolecule as well as the transfer agent are consumed during this process. However, there are also chain transfer reactions that generate new chain carriers and new chain transfer agents at the same time with significant consequences for the distribution of the (average) molecular weight distribution, the dispersity Đ and the (average) degree of polymerization of the product. These chain transfer reactions are called degenerative chain transfer reactions and are observed, for example in RAFT-, ITRP-, or TERP- processes. RAFT = reversible addition-fragmentation chain transfer polymerization; ITRP = iodine-transfer polymerization; TERP = telluride-mediated polymerization. These polymerization techniques belong to the class of reversible deactivation radical polymerizations (RDRP) that show some characteristics of a living polymerization, however, they must not be addressed as living polymerizations because true living polymerizations are characterized by the absence of any termination reaction.In this sense, a chain-transfer agent RX is a substance that is able to react with a chain carrier by a reaction in which the original chain P• is deactivated and a new chain carrier R• is generated, as shown above.".
- Degenerative_chain_transfer wikiPageExternalLink 0483.
- Degenerative_chain_transfer wikiPageID "39968404".
- Degenerative_chain_transfer wikiPageRevisionID "601866734".
- Degenerative_chain_transfer align "right".
- Degenerative_chain_transfer quote "Chain-transfer reaction that generates a new chain carrier".
- Degenerative_chain_transfer quote "and a new chain-transfer agent with the same reactivity".
- Degenerative_chain_transfer quote "as the original chain carrier and chain-transfer agent".
- Degenerative_chain_transfer source 0483.
- Degenerative_chain_transfer title "IUPAC definition for degenerative chain transfer".
- Degenerative_chain_transfer subject Category:Polymerization_reactions.
- Degenerative_chain_transfer comment "In polymer chemistry, degenerative chain transfer (also called degenerate chain transfer) is a process that can occur in a radical polymerization whereby reactivity of active centres are changed, hence significantly influencing the molecular weight distribution of the resulting product.In chain polymerization processes it is observed that during the chemical reactions an active centre on a growing chain is transferred from a growing macromolecule - P• - or oligomer to another molecule (transfer agent XR) or to another site on the same molecule.P• + XR → PX + R•This transfer involves termination of the initially growing chain to the completed macromolecule PX, where X denotes one end-group of the macromolecule. ".
- Degenerative_chain_transfer label "Degenerative chain transfer".
- Degenerative_chain_transfer sameAs m.0wblr5b.
- Degenerative_chain_transfer sameAs Q17104649.
- Degenerative_chain_transfer sameAs Q17104649.
- Degenerative_chain_transfer wasDerivedFrom Degenerative_chain_transfer?oldid=601866734.
- Degenerative_chain_transfer isPrimaryTopicOf Degenerative_chain_transfer.