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- Free-energy_relationship abstract "In physical organic chemistry, a free-energy relationship or linear Gibbs energy relation relates the logarithm of a reaction rate constant or equilibrium constant for one series of reactions with the logarithm of the rate or equilibrium constant for a related series of reactions. Establishing free-energy relationships helps in the understanding of the reaction mechanism for a chemical reaction and allows the prediction of reaction rates and equilibrium constants.The Brønsted catalysis equation describes the relationship between the ionization constant of a series of catalysts and the reaction rate constant for a reaction on which the catalyst operates.The Hammett equation predicts the equilibrium constant or reaction rate of a reaction from a substituent constant and a reaction type constant. The Edwards equation relates the nucleophilic power to polarisability and basicity.It has been suggested[citation needed] that this name should be replaced by linear Gibbs energy relation, but at present there is little sign of acceptance of this change.The area of physical organic chemistry which deals with such relations is commonly referred to as 'Linear Free-Energy Relationships'.".
- Free-energy_relationship wikiPageExternalLink L03551.html.
- Free-energy_relationship wikiPageExternalLink L03551.html.
- Free-energy_relationship wikiPageID "2057973".
- Free-energy_relationship wikiPageRevisionID "603315746".
- Free-energy_relationship hasPhotoCollection Free-energy_relationship.
- Free-energy_relationship subject Category:Physical_organic_chemistry.
- Free-energy_relationship subject Category:Solutions.
- Free-energy_relationship type Abstraction100002137.
- Free-energy_relationship type Matter100020827.
- Free-energy_relationship type Mixture114586258.
- Free-energy_relationship type Part113809207.
- Free-energy_relationship type PhysicalEntity100001930.
- Free-energy_relationship type Relation100031921.
- Free-energy_relationship type Solution114589223.
- Free-energy_relationship type Solutions.
- Free-energy_relationship type Substance100019613.
- Free-energy_relationship comment "In physical organic chemistry, a free-energy relationship or linear Gibbs energy relation relates the logarithm of a reaction rate constant or equilibrium constant for one series of reactions with the logarithm of the rate or equilibrium constant for a related series of reactions.".
- Free-energy_relationship label "Correlação linear de energia livre".
- Free-energy_relationship label "Free-energy relationship".
- Free-energy_relationship label "علاقة خطية للطاقة الحرة".
- Free-energy_relationship sameAs Correlação_linear_de_energia_livre.
- Free-energy_relationship sameAs m.06j40d.
- Free-energy_relationship sameAs Q4119007.
- Free-energy_relationship sameAs Q4119007.
- Free-energy_relationship sameAs Free-energy_relationship.
- Free-energy_relationship wasDerivedFrom Free-energy_relationship?oldid=603315746.
- Free-energy_relationship isPrimaryTopicOf Free-energy_relationship.