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- Kläui_ligand abstract "The Kläui ligand is the anion {(C5H5)Co[(CH3O)2PO]3}-. The ligand, popularized by Wolfgang Kläui, binds metals and metalloids via a facial O3 donor set. Related tridentate anionic ligands include trispyrazolylborate and cyclopentadienyl anions.The ligand is derived from the cationic complex of trimethylphosphite {(C5H5)Co[P(OCH3)3]3}2+ via an Arbuzov reaction. Using other phosphites and other cyclopentadienyl ligands, a large variety of derivatives are possible. The parent acid {(C5H5)Co[(CH3O)2PO]3}H is highly soluble in water (270 g/100 mL). Its pKa is about 2. Many complexes have been described, including bis(chelate) complexes of the type {M[{(C5H5)Co[(CH3O)2PO]3}2]n+ (M = Co(II), Mn(II), Bi(III), etc.).".
- Kläui_ligand thumbnail KlauiCmpx.png?width=300.
- Kläui_ligand wikiPageID "22689796".
- Kläui_ligand wikiPageRevisionID "602487939".
- Kläui_ligand subject Category:Cobalt_compounds.
- Kläui_ligand subject Category:Half_sandwich_compounds.
- Kläui_ligand comment "The Kläui ligand is the anion {(C5H5)Co[(CH3O)2PO]3}-. The ligand, popularized by Wolfgang Kläui, binds metals and metalloids via a facial O3 donor set. Related tridentate anionic ligands include trispyrazolylborate and cyclopentadienyl anions.The ligand is derived from the cationic complex of trimethylphosphite {(C5H5)Co[P(OCH3)3]3}2+ via an Arbuzov reaction. Using other phosphites and other cyclopentadienyl ligands, a large variety of derivatives are possible.".
- Kläui_ligand label "Kläui ligand".
- Kläui_ligand label "Kläui-Tripod-Ligand".
- Kläui_ligand sameAs Kl%C3%A4ui_ligand.
- Kläui_ligand sameAs Kläui-Tripod-Ligand.
- Kläui_ligand sameAs Q1776711.
- Kläui_ligand sameAs Q1776711.
- Kläui_ligand wasDerivedFrom Kläui_ligand?oldid=602487939.
- Kläui_ligand depiction KlauiCmpx.png.
