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- Molecular_sensor abstract "A molecular sensor or chemosensor is a molecule that interacts with an analyte to produce a detectable change. Molecular sensors combine molecular recognition with some form of reporter so the presence of the guest can be observed. The term supramolecular analytical chemistry has recently been coined to describe the application of molecular sensors to analytical chemistry.Early examples of molecular sensors are crown ethers with large affinity for sodium ions but not for potassium and forms of metal detection by so-called complexones which are traditional pH indicators retrofitted with molecular groups sensitive to metals. This receptor-spacer-reporter concept is a recurring theme often with the reporter displaying photoinduced electron transfer. One example is a sensor sensitive to heparin. Other receptors are sensitive not to a specific molecule but to a molecular compound class. One example is the grouped analysis of several tannic acids that accumulate in ageing Scotch whisky in oak barrels. The grouped results demonstrated a correlation with the age but the individual components did not. A similar receptor can be used to analyze tartrates in wine. The compound saxitoxin is a neurotoxin found in shellfish and a chemical weapon. An experimental sensor for this compound is again based on PET. Interaction of saxitoxin with the sensor's crown ether moiety kills its PET process towards the fluorophore and fluorescence is switched from off to on. The unusual boron moiety makes sure the fluorescence takes place in the visible light part of the electromagnetic spectrum In another strategy called indicator-displacement assay (IDA) an analyte such as citrate or phosphate ions displace a fluorescent indicator in an indicator-host complex. The so-called UT taste chip (University of Texas) is a prototype electronic tongue and combines supramolecular chemistry with charge-coupled devices based on silicon wafers and immobilized receptor molecules.".
- Molecular_sensor thumbnail SelectiveHeparinBinding.png?width=300.
- Molecular_sensor wikiPageID "9414430".
- Molecular_sensor wikiPageRevisionID "544682236".
- Molecular_sensor hasPhotoCollection Molecular_sensor.
- Molecular_sensor subject Category:Molecular_machines.
- Molecular_sensor subject Category:Supramolecular_chemistry.
- Molecular_sensor type Artifact100021939.
- Molecular_sensor type Device103183080.
- Molecular_sensor type Instrumentality103575240.
- Molecular_sensor type Machine103699975.
- Molecular_sensor type MolecularMachines.
- Molecular_sensor type Object100002684.
- Molecular_sensor type PhysicalEntity100001930.
- Molecular_sensor type Whole100003553.
- Molecular_sensor comment "A molecular sensor or chemosensor is a molecule that interacts with an analyte to produce a detectable change. Molecular sensors combine molecular recognition with some form of reporter so the presence of the guest can be observed.".
- Molecular_sensor label "Molecular sensor".
- Molecular_sensor label "مستشعر جزيئي".
- Molecular_sensor sameAs m.0287ycl.
- Molecular_sensor sameAs Q3743702.
- Molecular_sensor sameAs Q3743702.
- Molecular_sensor sameAs Molecular_sensor.
- Molecular_sensor wasDerivedFrom Molecular_sensor?oldid=544682236.
- Molecular_sensor depiction SelectiveHeparinBinding.png.
- Molecular_sensor isPrimaryTopicOf Molecular_sensor.
