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- NOBIN abstract "NOBIN (2-amino-2'-hydroxy-1,1'-binaphthyl) is an organic molecule used for asymmetric catalysis. NOBIN is related to BINOL and other analogs by both having a chiral axis and being a scaffold for certain chemical reactions. NOBIN is an excellent catalyst for the aldol reaction producing reliable products, good yields, and excellent diastereoselectivity.Though rotation around the bond joining the rings is limited by the hydrogen atoms, enantiomerically pure NOBIN may racemize upon heating.NOBIN is prepared by oxidative cross coupling of 2-naphthol and 2-naphthylamine. The oxidative source is metal ions in solution such as Fe2+ or a Cu2+ amine complex. Once racemic NOBIN is produced, it needs to be resolved. One method for this is the use of camphorsulfonic acid, in which the basic group of NOBIN is used to form a diastereomeric salt of one enantiomer. The other enantiomer however will stay in solution.".
- NOBIN iupacName "2-Amino-2′-hydroxy-1,1′-binaphthalene".
- NOBIN thumbnail NOBIN.png?width=300.
- NOBIN wikiPageID "12060033".
- NOBIN wikiPageRevisionID "490627577".
- NOBIN hasPhotoCollection NOBIN.
- NOBIN imagefile "NOBIN.png".
- NOBIN imagesize "180".
- NOBIN iupacname "2".
- NOBIN othernames "2".
- NOBIN verifiedrevid "440512804".
- NOBIN subject Category:2-Naphthols.
- NOBIN subject Category:Catalysts.
- NOBIN subject Category:Naphthylamines.
- NOBIN type Abstraction100002137.
- NOBIN type Activator114723079.
- NOBIN type Catalyst114723628.
- NOBIN type Catalysts.
- NOBIN type Matter100020827.
- NOBIN type Part113809207.
- NOBIN type PhysicalEntity100001930.
- NOBIN type Relation100031921.
- NOBIN type Substance100019613.
- NOBIN type ChemicalCompound.
- NOBIN type ChemicalSubstance.
- NOBIN type ChemicalSubstanceType.
- NOBIN type ChemicalObject.
- NOBIN type Thing.
- NOBIN comment "NOBIN (2-amino-2'-hydroxy-1,1'-binaphthyl) is an organic molecule used for asymmetric catalysis. NOBIN is related to BINOL and other analogs by both having a chiral axis and being a scaffold for certain chemical reactions.".
- NOBIN label "NOBIN".
- NOBIN sameAs m.02vnh32.
- NOBIN sameAs Q6954850.
- NOBIN sameAs Q6954850.
- NOBIN sameAs NOBIN.
- NOBIN wasDerivedFrom NOBIN?oldid=490627577.
- NOBIN depiction NOBIN.png.
- NOBIN isPrimaryTopicOf NOBIN.
