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- Nitrilimine abstract "Nitrilimines or nitrile amides are a class of organic compounds sharing a common functional group with the general structure R-CN-NR corresponding to the conjugate base of an amine bonded to the N-terminus of a nitrile. The dominant structure for the parent compound nitrilimine is that of the propargyl-like 1 in scheme 1 with a C-N triple bond and with a formal positive charge on nitrogen and two lone pairs and a formal negative charge on the terminal nitrogen. Other structures such as hypervalent 2, allene-like 3, allylic 4 and carbene 5 are of lesser relevance.Nitrilimines were first observed in the thermal decomposition of 2-tetrazoles releasing nitrogen:Nitrilimines are linear 1,3-dipoles represented by structures 1 and 3. A major use is in heterocyclic synthesis. E.g. with alkynes they generate pyrazoles in a 1,3-dipolar cycloaddition. Due to their high energy, they are usually generated in situ as a reactive intermediate.".
- Nitrilimine thumbnail NitrilimineStructures.png?width=300.
- Nitrilimine wikiPageID "4323960".
- Nitrilimine wikiPageRevisionID "544313465".
- Nitrilimine hasPhotoCollection Nitrilimine.
- Nitrilimine subject Category:Functional_groups.
- Nitrilimine type Abstraction100002137.
- Nitrilimine type FunctionalGroups.
- Nitrilimine type Group100031264.
- Nitrilimine comment "Nitrilimines or nitrile amides are a class of organic compounds sharing a common functional group with the general structure R-CN-NR corresponding to the conjugate base of an amine bonded to the N-terminus of a nitrile. The dominant structure for the parent compound nitrilimine is that of the propargyl-like 1 in scheme 1 with a C-N triple bond and with a formal positive charge on nitrogen and two lone pairs and a formal negative charge on the terminal nitrogen.".
- Nitrilimine label "Nitrilimina".
- Nitrilimine label "Nitrilimine".
- Nitrilimine label "Nitrilimine".
- Nitrilimine sameAs Nitrilimina.
- Nitrilimine sameAs Nitrilimine.
- Nitrilimine sameAs m.0bx3p0.
- Nitrilimine sameAs Q3342206.
- Nitrilimine sameAs Q3342206.
- Nitrilimine sameAs Nitrilimine.
- Nitrilimine wasDerivedFrom Nitrilimine?oldid=544313465.
- Nitrilimine depiction NitrilimineStructures.png.
- Nitrilimine isPrimaryTopicOf Nitrilimine.
